Leire Sangroniz Agudo


Coordinator

Física de polímeros multifásicos avanzados

Física de polímeros y fabricación avanzada

+34943018494

leire.sangroniz@ehu.eus



Dr. Leire Sangroniz Agudo is a La Caixa Junior Leader Postdoctoral Fellow and Emakiker Fellow at POLYMAT, and a Ramón y Cajal awardee at POLYMAT and the University of the Basque Country (UPV/EHU). She earned her BSc in Chemistry (2014) and MSc in Chemistry and Polymers (2015) from UPV/EHU, where she also obtained her PhD in 2019 with Prof. A. Santamaria and Prof. A.J. Müller with the support of a competitive individual FPU fellowship at national level. In 2020, she was awarded the highest-ranked postdoctoral fellowship from the Basque Government, enabling her to join Prof. Marc A. Hillmyer's group at the University of Minnesota and become part of the Center for Sustainable Polymers (CSP). In 2023, she continued her postdoctoral research at the University of Genoa (Italy) joining the group of Prof. Dario Cavallo with a Margarita Salas Fellowship. After that period, she returned to POLYMAT in 2024 to implement her research line. Her scientific achievements have been recognized through several prestigious awards, including the Iberian Award for the Most Distinguished PhD Thesis in Rheology (2019–2021), jointly presented by the Spanish Rheology Group and the Portuguese Society of Rheology (2022), the Extraordinary PhD Thesis Award from UPV/EHU (2022) and CAF-Elhuyar Award (2020). More recently, she received the European Polymer Federation Future Faculty and Researchers Award (2025) and the JTACC+V4 Young Scientist Award (2025) for her outstanding contributions to polymer science. Her research focuses on developing next-generation semicrystalline sustainable polymers by replacing conventional petroleum-based materials with renewable, biodegradable, and chemically recyclable alternatives. Her research aims to establish fundamental structure–property relationships governing polymer crystallization and processing to enable the rational design of high-performance sustainable polymeric materials.

Tacticity-independent crystallization of polymers
L. Sangroniz, A. Sangroniz, C. Shi, M. Scoti, M. Ximenis, C. De Rosa, E. Chen, H. Sardon and A.J. Müller
Nature Chemistry Vol. 18, Núm. 4, pp. 625–638 10.1038/s41557-026-02113-w 03/04/2026
Polymorphic Self-Poisoning in the Isothermal Crystallization of Thermoplastic Polyurethanes
Z. Baouch, I. Guardincerri, K. Jariyavidyanont, L. Sangroniz, Y. Shi, E. Poselt, A.J. Müller, R. Androsch and D. Cavallo
MACROMOLECULES Vol. 59, Núm. 2, pp. 950–961 10.1021/acs.macromol.5c02761 08/01/2026
Decoupling the Roles of Chain Length, Entanglements, and Intermolecular Interactions on the Melt Memory of Semicrystalline Polar Homopolymers
Aboudzadeh M.A., Sangroniz L., Coulembier O., Ferranti M., Costanzo S., Grizzuti N., Cavallo D. and A.J. Müller
MACROMOLECULES Vol. 59, Núm. 6, pp. 3371–3383 10.1021/acs.macromol.5c03323 01/01/2026
How the lack of chain ends affects the melt memory of poly(ethylene oxide): cyclic versus linear chains
Sangroniz L., Barroso-Bujans F., Allgaier J. and A.J. Müller
POLYMER Vol. 358 10.1016/j.polymer.2026.130193 01/01/2026
Impact of Chain Length on PCL Dielectric ß-Relaxation: Decoupling the Roles of Chain Ends, Main Chains, Entanglements, and Crystallinity
L. Sangroniz, A. Alegria and A.J. Müller
MACROMOLECULES Vol. 58, Núm. 23, pp. 12552–12563 10.1021/acs.macromol.5c01395 25/11/2025
Self-Nucleation Enables Polymorphic Selection in Thermoplastic Polyurethanes
Z. Baouch, L. Sangroniz, Y. Shi, E. Poselt, A.J. Müller and D. Cavallo
MACROMOLECULES Vol. 58, Núm. 18, pp. 9876–9886 10.1021/acs.macromol.5c01477 12/09/2025
Effect of Side-Chain gem-dialkyl Substitution on the Crystallization of poly(d-valerolactone): Competition between Steric Effects and Chain Flexibility
L. Sangroniz, J. Ramos, J. Vega, X. Li, T. Xu, E. Chen, A.J. Müller and D. Cavallo
ACS Sustainable Chemistry & Engineering Vol. 13, Núm. 33, pp. 13386–13398 10.1021/acssuschemeng.5c04491 25/08/2025
Pasteurization-Triggered Heat-Resistant Enhancement of Packaging Films Derived from a Star-Shape Toughened Polylactide Stereocomplex
S. Buchatip, W. Supmak, L. Sangroniz, M. Opaprakasit, A. Petchsuk, P. Opaprakasit and A.J. Müller
ACS Omega Vol. 10, Núm. 29, pp. 32015–32028 10.1021/acsomega.5c03596 29/07/2025
Lamellar thickness of the polypropylene matrix determines surface induced nucleation of polyethylene droplets in immiscible blends
L. Sangroniz, E. Carmeli, L. Vukusic, V. Hristov, M. Galatini, D. Tranchida and D. Cavallo
POLYMER Vol. 321 10.1016/j.polymer.2025.128144 01/01/2025
Effect of Biobased Glycerol Trilevulinate on the Crystallization Kinetics of Biodegradable Polyesters
F. Shariatikia, L. Sangroniz, J. Olmedo-Martínez, R. Pérez-Camargo, A. González, L. Lenzi, M. Degli Esposti, D. Morselli, P. Fabbri and A.J. Müller
ACS Sustainable Chemistry & Engineering Vol. 13, Núm. 12, pp. 4884–4896 10.1021/acssuschemeng.5c00178 01/01/2025
Cooling rate-dependent polymorphism in thermoplastic polyurethanes: effect of hard segments content
Z. Baouch, K. Jariyavidyanont, L. Moni, L. Sangroniz, E. Pöselt, A.J. Müller, R. Androsch and D. Cavallo
POLYMER Vol. 328 10.1016/j.polymer.2025.128477 01/01/2025
The Decisive Role of Confinement in Enhancing or Suppressing Self-Nucleation in Polyethylene-Containing Block Copolymers
Y. Liao, L. Sangroniz, M. Safari, H. Schmalz and A.J. Müller
MACROMOLECULAR CHEMISTRY AND PHYSICS Vol. 226, Núm. 14 10.1002/macp.202500056 01/01/2025
Melt memory effect on crystallization in olefin copolymers: Is random comonomer incorporation the only requirement?
L. Sangroniz, M. Fernandéz, G. Leone and D. Cavallo
POLYMER Vol. 338 10.1016/j.polymer.2025.129038 01/01/2025
Fungal Chitin Nanofibrils to Improve the Functional Properties of Poly(vinyl alcohol) Films for Sustainable Food Packaging
M. Alam, L. Sangroniz, M. Scoti, A. González, A. Etxeberría, A. Sangroniz and E. Lizundia
ACS Applied Bio Materials Vol. 8, Núm. 11, pp. 10381–10392 10.1021/acsabm.5c01723 01/01/2025
Origin of Melt Memory Effects in Poly(ethylene oxide): The Crucial Role of Entanglements
L. Sangroniz, A.J. Müller and D. Cavallo
MACROMOLECULAR RAPID COMMUNICATIONS Vol. 45, Núm. 12 10.1002/marc.202400011 01/01/2024
Crystallization-Induced Self-Assembly of Poly(ethylene glycol) Side Chains in Dithiol-yne-Based Comb Polymers: Side Chain Spacing and Molecular Weight Effects
E. Matxinandiarena, M. Peñas, B. Curole, M. Król, L. Polo Fonseca, J. Ruokolainen, S. Grayson, L. Sangroniz and A.J. Müller
MACROMOLECULES Vol. 57, Núm. 10, pp. 4906–4917 10.1021/acs.macromol.4c00527 01/01/2024
Polymer Physics behind the Gel-Spinning of UHMWPE Fibers
Z. Wang, L. Sangroniz, J. Xu, C. Zhu and A.J. Müller
MACROMOLECULAR RAPID COMMUNICATIONS Vol. 45, Núm. 15 10.1002/marc.202400124 01/01/2024
Strong Hydrogen Bonds Sustain Even-Odd Effects in Poly(ester amide)s with Long Alkyl Chain Length in the Backbone
L. Sangroniz, J. Olmedo-Martínez, W. Hu, Y. Jang, G. Liu, M. Hillmyer and A.J. Müller
BIOMACROMOLECULES Vol. 25, Núm. 11, pp. 7500–7510 10.1021/acs.biomac.4c01191 01/01/2024
Control over Aspect Ratio and Polymer Spatial Distribution of 2D Platelets via Living Crystallization-Driven Self-Assembly
T. Xia, L. Xiao, K. Sun, J. Rho, Y. Xie, S. Parkinson, L. Sangroniz, J. Zhang, J. Lin, A.J. Müller, L. Gao, A. Dove and R. O’Reilly
MACROMOLECULES Vol. 57, Núm. 23, pp. 11210–11220 10.1021/acs.macromol.4c02496 01/01/2024
Disappearance of Melt Memory Effect with Comonomer Incorporation in Isodimorphic Random Copolyesters
L. Sangroniz, M. Safari, A. de Ilarduya, H. Sardon, D. Cavallo and A.J. Müller
MACROMOLECULES Vol. 56, Núm. 19, pp. 7879–7888 10.1021/acs.macromol.3c01389 21/09/2023
Tuning the crystallization and thermal properties of polyesters by introducing functional groups that induce intermolecular interactions
L. Sangroniz, Y. Jang, M. Hillmyer and A.J. Müller
JOURNAL OF CHEMICAL PHYSICS Vol. 159, Núm. 8 10.1063/5.0165951 28/08/2023
Polymers and rheology: A tale of give and take
L. Sangroniz, M. Fernández and A. Santamaria
POLYMER Vol. 271 10.1016/j.polymer.2023.125811 01/01/2023
Effect of Molecular Weight on the Crystallization and Melt Memory of Poly(?-caprolactone) (PCL)
A. Fernández-Tena, R. Pérez-Camargo, O. Coulembier, L. Sangroniz, N. Aranburu, G. Guerrica-Echevarria, G. Liu, D. Wang, D. Cavallo and A.J. Müller
MACROMOLECULES Vol. 56, Núm. 12, pp. 4602–4620 10.1021/acs.macromol.3c00234 01/01/2023
The role of intermolecular interactions on melt memory and thermal fractionation of semicrystalline polymers
L. Sangroniz, Y. Jang, M. Hillmyer and A.J. Müller
JOURNAL OF CHEMICAL PHYSICS Vol. 156, Núm. 14 10.1063/5.0087782 14/04/2022
Lactide-valerolactone copolymers for packaging applications
Sangroniz A., Sangroniz L., Hamzehlou S., Aranburu N., Sardon H., J.R. Sarasua, Iriarte M., J.R. Leiza and Etxeberria A.
Polymers Vol. 14, Núm. 1 10.3390/polym14010052 01/01/2022
Fractionated crystallization in semicrystalline polymers
L. Sangroniz, B. Wang, Y. Su, G. Liu, D. Cavallo, D. Wang and A.J. Müller
PROGRESS IN POLYMER SCIENCE Vol. 115 10.1016/j.progpolymsci.2021.101376 01/01/2021
Matching rheology, conductivity and joule effect in PU/CNT nanocomposites
L. Sangroniz, M. Landa, M. Fernández and A. Santamaria
Polymers Vol. 13, Núm. 6 10.3390/polym13060950 01/01/2021
Rheology of complex biobased quaternary blends: Poly(lactic acid) [poly(ethylene oxide)]/poly(ether-b-amide)/poly(amide 11)
L. Sangroniz, T. Gancheva, B. Favis, A.J. Müller and A. Santamaria
JOURNAL OF RHEOLOGY Vol. 65, Núm. 3, pp. 437–451 10.1122/8.0000202 01/01/2021
Rheology of polymer processing in Spain (1995–2020)
L. Sangroniz, M. Fernández, P. Partal and A. Santamaria
Polymers Vol. 13, Núm. 14 10.3390/polym13142314 01/01/2021
Chemical Structure Drives Memory Effects in the Crystallization of Homopolymers
L. Sangroniz, A. Sangroniz, L. Meabe, A. Basterretxea, H. Sardon, D. Cavallo and A.J. Müller
MACROMOLECULES Vol. 53, Núm. 12, pp. 4874–4881 10.1021/acs.macromol.0c00751 23/06/2020
Effect of shear rate and pressure on the crystallization of PP nanocomposites and PP/PET polymer blend nanocomposites
L. Sangroniz, M. van Drongelen, R. Cardinaels, A. Santamaria, G. Peters and A.J. Müller
POLYMER Vol. 186 10.1016/j.polymer.2019.121950 09/01/2020
Self-Nucleation Effects on Polymer Crystallization
L. Sangroniz, D. Cavallo and A.J. Müller
MACROMOLECULES Vol. 53, Núm. 12, pp. 4581–4604 10.1021/acs.macromol.0c00223 01/01/2020
Properties of scaffolds prepared by fused deposition modeling of poly(hydroxyalkanoates)
A. Kovalcik, L. Sangroniz, M. Kalina, K. Skopalova, P. Humpolícek, M. Omastova, N. Mundigler and A.J. Müller
International Journal of Biological Macromolecules Vol. 161, pp. 364–376 10.1016/j.ijbiomac.2020.06.022 01/01/2020
Lactide-caprolactone copolymers with tuneable barrier properties for packaging applications
A. Sangroniz, L. Sangroniz, S. Hamzehlou, J. Río, A. Santamaria, J.R. Sarasua, M. Iriarte, J.R. Leiza and A. Etxeberria
POLYMER Vol. 202 10.1016/j.polymer.2020.122681 01/01/2020
Melt memory effects in poly(Butylene succinate) studied by differential fast scanning calorimetry
L. Sangroniz, C. Ocando, D. Cavallo and A.J. Müller
Polymers Vol. 12, Núm. 12, pp. 1–18 10.3390/polym12122796 01/01/2020
Upgrading Recycled Polyolefins as Stimuli Responsive Materials
L. Sangroniz, A. Sangroniz, M. Fernandez, A. Etxeberria, A.J. Müller and A. Santamaria
Proceedings Of The Iberian Meeting On Rheology (ibereo 2019) pp. 100–103 10.1007/978-3-030-27701-7_21 01/01/2020
Reactive melt processing of poly (L-lactide) in the presence of thermoplastic polyurethane and carboxylated carbon nanotubes
O. Yousetzade, J. Ugartemendia, L. Sangroniz, R. Hernandez, J. Puiggali and H. Garmabi
JOURNAL OF MATERIALS SCIENCE Vol. 54, Núm. 24, pp. 14961–14974 10.1007/s10853-019-03889-8 01/12/2019
Improving the barrier character of poly(caprolactone): Transport properties and free volume of immiscible blends
S. Eceolaza, A. Sangroniz, J. del Rio, M. Iriarte and A. Etxeberria
JOURNAL OF APPLIED POLYMER SCIENCE Vol. 136, Núm. 40 10.1002/app.48018 20/10/2019
Packaging materials with desired mechanical and barrier properties and full chemical recyclability
A. Sangroniz, J. Zhu, X. Tang, A. Etxeberria, E. Chen and H. Sardon
Nature Communications Vol. 10, Núm. 1 10.1038/s41467-019-11525-x 08/08/2019
Elaboration and Characterization of Conductive Polymer Nanocomposites with Potential Use as Electrically Driven Membranes
L. Sangroniz, A. Sangroniz, M. Fernandez, A. Etxeberria, A.J. Müller and A. Santamaria
Polymers Vol. 11, Núm. 7 10.3390/polym11071180 01/07/2019
Improving the barrier properties of a biodegradable polyester for packaging applications
A. Sangroniz, L. Sangroniz, A. Gonzalez, A. Santamaria, J. del Rio, M. Iriarte and A. Etxeberria
EUROPEAN POLYMER JOURNAL Vol. 115, pp. 76–85 10.1016/j.eurpolymj.2019.03.026 01/06/2019
Polyethylene terephthalate/low density polyethylene/titanium dioxide blend nanocomposites: Morphology, crystallinity, rheology, and transport properties
L. Sangroniz, J. Ruiz, A. Sangroniz, M. Fernandez, A. Etxeberria, A.J. Müller and A. Santamaria
JOURNAL OF APPLIED POLYMER SCIENCE Vol. 136, Núm. 4 10.1002/app.46986 20/01/2019
Plasticization of poly(lactide) with poly(ethylene glycol): Low weight plasticizer vs triblock copolymers. Effect on free volume and barrier properties
A. Chaos, A. Sangroniz, J. Fernandez, J. del Rio, M. Iriarte, J.R. Sarasua and A. Etxeberria
JOURNAL OF APPLIED POLYMER SCIENCE Vol. 137, Núm. 28 10.1002/app.48868 01/01/2019
Effect of hydrogen bonding on the physicochemical and rheological features of chemically modified phenoxy
L. Sangroniz, A. Sangroniz, A. Alegria, M. Fernandez, L. Irusta, A.J. Müller, A. Etxeberria and A. Santamaria
POLYMER Vol. 159, pp. 12–22 10.1016/j.polymer.2018.11.002 20/12/2018
Blends based on biodegradable poly(butylene adipate-co-terephthalate) for packaging: Degradation and transport properties
A. Sangroniz, L. Sangroniz, A. Santamaria, M. Iriarte and A. Etxeberria
Abstracts Of Papers Of The American Chemical Society Vol. 256 000447609104602 19/08/2018
Studying the effect of hydrogen bonds on an amorphous thermoplastic
A. Sangroniz, L. Sangroniz, A.J. Müller, M. Iriarte, A. Santamaria and A. Etxeberria
Abstracts Of Papers Of The American Chemical Society Vol. 256 000447609105479 19/08/2018
Blends of biodegradable poly(butylene adipate-co-terephthalate) with poly (hydroxi amino ether) for packaging applications: Miscibility, rheology and transport properties
A. Sangroniz, L. Sangroniz, N. Aranburu, M. Fernandez, A. Santamaria, M. Iriarte and A. Etxeberria
EUROPEAN POLYMER JOURNAL Vol. 105, pp. 348–358 10.1016/j.eurpolymj.2018.06.016 01/08/2018
Differences between Isotropic and Self-Nucleated PCL Melts Detected by Dielectric Experiments
L. Sangroniz, R. Alamo, D. Cavallo, A. Santamaria, A.J. Müller and A. Alegria
MACROMOLECULES Vol. 51, Núm. 10, pp. 3663–3671 10.1021/acs.macromol.8b00708 22/05/2018