Haritz Sardon


Research Staff

Coordinator

Reciclaje de polímeros

Polímeros y sostenibilidad

Catálisis sostenible

+34943015303

haritz.sardon@ehu.es



Dr. Haritz Sardon Muguruza earned his BS in Chemistry and his MS in Applied Chemistry and Polymeric Materialsfrom the University of the Basque Country (UPV-EHU). He got his PhD also from the UPV-EHU with the especial mention of "Doctor Europeus". During the mentioned PhD, he spent 6 months at Laboratoire de Chimie et Procédés de Polymérisation (LCPP), CNRS, Villeurbanne, France under the supervision of Dr. Elodie Bourgeat-Lami and Dr. Muriel Lansalot. He held a postdoctoral researcher position at IBM-Almaden Research Center (SanJose, California) in 2012 to work with Dr. James L. Hedrick. There, he developed sustainable approaches for the synthesis of polyurethanes using isocyanate and metal-free methods as part of IBM´s smart planet initiative. The goal was to synthesize "smart" polymers that execute useful biological functions on the nanoscale, e.g. selectivity delivering drugs to tumors, killing pathogens without harming human cells, etc using organocatalysis. In 2014, as part of his postdoctoral training, he spent 5 months in the group of Vygodskii (INEOS, Russia), working on the synthesis of ionic cationic diols to enhance the CO2 separation in polyurethane membranes.Nowadays, he is coordinating a Marie Skłodowska-Curie European Joint Doctorate Training Network (ITN-EJD) in sustainable polymerization processes (SUSPOL). And supervising 3 PhD students inside this european network. In 2011, he was awarded with a Post-doctoral grant from the Basque Government. In 2014 he was awarded with a “Juan de la Cierva” award. Also in 2014, he was awarded with Iberdrola Research Project for young researchers in energy and environment.   In 2016 he took an Ikerbasque Research Fellow position between the BERC-POLYMAT and the University of Basque Country to start his independent research lines. His overall research aims to prepare new functional polymeric materials using sustainable polymerization processes for advanced engineering and biomedical applications. Specially, using “green” polymerization processes such as monomers from polymer recycling, reagents from renewable sources or the use of less hazardous organocatalysts to prepare high added value polymers. Our overall research aims to prepare new functional polymeric materials using sustainable polymerization processes for advanced engineering and biomedical applications. Specially, our investigations involve the synthesis of new polymers using “green” polymerization processes such as monomers from polymer recycling, reagents from renewable sources or the use of less hazardous organocatalysts to prepare not only biodegradable polymeric materials for nanomedicine but also high added value polymers. Our group combines expertise in polymer chemistry, organic synthesis, nanomedicine and material science.    Research lines:   1. Sustainable Polymerization: We work in the chemical recycling of commodity polymers such as polyesters, polycarbonates and/or polyurethanes to prepare new monomers for highly added value applications. We are also interested in the utilization of less hazardous organocatalysts to prepare new polymers.    2. Polymers for nanomedicine: the good control of the polymerization processes and the utilization of benign polymerization conditions allow us to synthesize functional polymers that can be employed in biomedical applications. We are currently developing polymer for antimicrobial drug and gene delivery or magnetic resonance imaging applications. 

Quantum-Chemical Study for Understanding the Low Incorporationof 2-Methylen-1,3-Dioxepane (MDO) in Radical Ring-Opening Copolymerizationwith Vinyl Monomers
M. Irigoyen, A. Marchand, X. de Pariza, T. Melchin, A. Barquero, J. Matxain, H. Sardon, J.R. Leiza and F. Ruiperez
MACROMOLECULES Vol. 59, Núm. 14, pp. 8509–8521 10.1021/acs.macromol.6c00681 28/07/2026
Unique Hierarchical Mesostructures Arising from Biobased Double-Crystalline PLLA-b-PHDO-b-PLLA ABA Triblock Copolymers
F. Kilens, L. Fonseca, A. Olazabal, L. Unanue, J. Olmedo-Martinez, M. Krol, D. Mantione, N. Reis, A. Dove, H. Sardon, A.J. Müller and C. Jehanno
BIOMACROMOLECULES Vol. 27, Núm. 7, pp. 4844–4857 10.1021/acs.biomac.6c00880 16/06/2026
Towards selective recycling technologies for complex plastic waste
M. Ximenis, C. Jehanno, L. Breloy, O. Akin, R. Kol, K. Van Geem, S. De Meester and H. Sardón
Nature Reviews Materials Vol. 11, Núm. 8, pp. 632–652 10.1038/s41578-026-00927-1 01/06/2026
Catalyst-Controlled Dual Dynamic Networks in Polyhydroxyurethanes from Six-Membered Cyclic Carbonates (vol 227, e00498, 2026)
P. Bron, N. Arnould, L. Soares, D. Wolosz, A. Gonzalez, L. Irusta, H. Sardon, S. Caillol, V. Ladmiral and C. Bakkali-Hassani
MACROMOLECULAR CHEMISTRY AND PHYSICS Vol. 227, Núm. 9 10.1002/macp.70257 15/05/2026
Tacticity-independent crystallization of polymers
L. Sangroniz, A. Sangroniz, C. Shi, M. Scoti, M. Ximenis, C. De Rosa, E. Chen, H. Sardon and A.J. Müller
Nature Chemistry Vol. 18, Núm. 4, pp. 625–638 10.1038/s41557-026-02113-w 03/04/2026
Degradable Water-Swellable Elastomers from Biobased Deep Eutectic Monomers
L. Navarro, M. Hartman, S. Locatelli, S. Vaillard, M. Picchio, R. Minari, H. Sardon and D. Mecerreyes
ACS Sustainable Chemistry & Engineering Vol. 14, Núm. 14, pp. 6704–6718 10.1021/acssuschemeng.5c13563 31/03/2026
Synthesis and Properties of Poly(ethylene dodecanedioate)/Poly(dimethylsiloxane) and Poly(butylene dodecanedioate)/Poly(dimethylsiloxane) Copolymers: Synergistically Enhanced Mechanical Properties, Hydrophobicity, and Antifouling Performance
L. Huang, H. Sardon, G. Cao, X. Wang, W. Zhen and L. Zheng
ACS Applied Polymer Materials Vol. 8, Núm. 7, pp. 5238–5247 10.1021/acsapm.6c00428 20/03/2026
4D-Printable Poly(Thio)urethane Photoresins With Reactive Oxygen Species Responsiveness and Anti-Inflammatory Functionality
X. Lopez de Pariza, L. Arevalo-Lagos, L. Breloy, O. Varela, A. Larranaga, J. Cadavid-Vargas, O. Garagarza-Goienetxea, M. Moya-Granados, V. Bagnarello, H. Sardon and M. Criado-Gonzalez
ADVANCED FUNCTIONAL MATERIALS Vol. 36, Núm. 35 10.1002/adfm.202530585 28/01/2026
Solvent switch strategy to facilitate the downstream process of chemical recycling of plastics
E. Luna, I. Olazabal, T. de Somer, P. Nachtergaele, X. López, M. Ximenis, S. de Meester and H. Sardón
RESOURCES CONSERVATION AND RECYCLING Vol. 226 10.1016/j.resconrec.2025.108686 01/01/2026
Photobase generators for amino acid N-carboxyanhydride ring-opening photopolymerization: rapid access to degradable polypeptide-based networks
R. Murphy, C. Gonzato, F. Vidal, O. Varela, H. Sardón, O. Soppera and A. Heise
Polymer Chemistry Vol. 17, Núm. 10, pp. 989–994 10.1039/d6py00091f 01/01/2026
Tailored ZIF-8 morphologies enable efficient chemical recycling of polycarbonate waste
P. Jutrzenka Trzebiatowska, M. Baluk, I. Olazabal, M. Gazda, G. Perli, H. Sardon, M. Giménez-Marqués and A. Zaleska-Medynska
Journal of Environmental Chemical Engineering Vol. 14, Núm. 2 10.1016/j.jece.2026.121736 01/01/2026
Catalyst-Controlled Dual Dynamic Networks in Polyhydroxyurethanes from Six-Membered Cyclic Carbonates
P. Bron, N. Arnould, L. Soares, D. Wolosz, A. Gonzàles, L. Irusta, H. Sardon, S. Caillol, V. Ladmiral and C. Bakkali-Hassani
MACROMOLECULAR CHEMISTRY AND PHYSICS Vol. 227, Núm. 4 10.1002/macp.202500498 01/01/2026
Bioinspired catechol-based photocurable tissue sealants
López-Moral A., Moreno-Villaécija M.Á., Suárez-García S., Bolaños-Cardet J., Sedó-Vegara J., Alibés R., Mancebo-Aracil J., Sardon H., Lee H., Roscini C., Sangermano M., Busqué F. and Ruiz-Molina D.
Materials Today Chemistry Vol. 54 10.1016/j.mtchem.2026.103634 01/01/2026
Iron-Based Lewis/Brønsted Deep Eutectic Solvents for the Hydrolysis of Nylon-6,6
Rollo M., Rastelli F., Ximenis M., Martinelli E., Ciancaleoni G. and Sardon H.
Engineering Vol. 58, pp. 106–113 10.1016/j.eng.2026.02.001 01/01/2026
Non-isocyanate polyurethane foams: where we stand and what comes next?
Grignard B., Bourguignon M., Monie F., Vidil T., Cramail H., Perli G., Sardon H., Raquez J.-M., Caillol S. and Detrembleur C.
CHEMICAL SOCIETY REVIEWS Vol. 55, Núm. 9, pp. 4960–5004 10.1039/d5cs00144g 01/01/2026
Advances in Polyurethane Synthesis, From 2010 to 2025
Fonseca L.P., Lopez de Pariza X., de Morais Zanata D., Lima de Menezes R.N. and Sardon H.
Comprehensive Polymer Science pp. 1506–1561 10.1016/B978-0-323-95486-0.00162-9 01/01/2026
Stepwise enzymatic synthesis of stereoregular poly(hydroxyalkanoates) starting from prochiral ß-Keto esters
Maiz-Iginitz A., Andrés-Sanz D., Gabirondo E., Molteni L., Sardon H. and López-Gallego F.
BIORESOURCE TECHNOLOGY Vol. 459 10.1016/j.biortech.2026.135184 01/01/2026
Continuous and Divergent Biotransformation of ß-Ketoesters Into Enantiomerically Pure ß-Hydroxyacids or Their Oligomers Through a Telescoped Multienzyme Cascade
Pota G., Andrés-Sanz D., Maiz-Iginitz A., Armendáriz-Ruiz M.A., Sardon H., Vitiello G., Califano V., Costantini A. and López-Gallego F.
CHEMBIOCHEM Vol. 27, Núm. 14 10.1002/cbic.70474 01/01/2026
High-Molecular-Weight Isodimorphic Copolyesters with Tunable Ductility, Barrier Performance, and Adhesive Behavior
Torres-Rodríguez J., Pérez-Camargo R.A., Vidal F., Mantione D., Martínez de Ilarduya A., Aranburu N., Otaegi I., Calafel M.I., Fernandez M., Alam M.S., Sangroniz A., Sardon H. and A.J. Müller
ACS Sustainable Chemistry & Engineering Vol. 14, Núm. 31, pp. 14078–14090 10.1021/acssuschemeng.6c04613 01/01/2026
Polyamide depolymerization: unlocking polymer dissolution with dicarboxylic acids
M. Mestre-Membrado, I. Olazabal, L. Breloy, M. Irigoyen, J. Jordens, K. Vanbroekhoven, K. Elst and H. Sardon
GREEN CHEMISTRY Vol. 28, Núm. 5, pp. 2342–2354 10.1039/d5gc04670j 12/12/2025
Peculiar even-odd effect in semi-crystalline poly(alkylene succinate)s with a wide range of repeating unit chain lengths
J. Torres-Rodriguez, A. Martinez De Ilarduya, H. Sardon, R. Perez-Camargo and A.J. Müller
GREEN CHEMISTRY Vol. 27, Núm. 48, pp. 15548–15567 10.1039/d5gc05522a 11/11/2025
Enhancing the Self-Assembly of Step-Growth Polymers by Narrowing Their Molar Mass Distribution: A Dynamic Bond-Mediated Approach
L. Polo Fonseca, S. Hamzehlou, O. Garagarza, D. Mantione, A. Lamas, X. de Pariza, F. Elizalde, M. Campins, A. Agirre, G. Perli and H. Sardon
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Vol. 64, Núm. 39 10.1002/anie.202509710 17/08/2025
Selective chemical recycling of polyhydroxybutyrate into high-value hydroxy acid using the taurine organocatalyst
E. Gabirondo, A. Maiz-Iginitz, M. Ximenis, K. Swiderek, D. Andres-Sanz, V. Moliner, L. Cabedo, A. Westlie, E. Chen, D. Cerron-Infantes, M. Unterlass, F. Lopez-Gallego, A. Etxeberria and H. Sardon
Chemical Science Vol. 16, Núm. 32, pp. 14509–14517 10.1039/d5sc02196k 13/08/2025
A continuous flow based irreversible polycondensation enables synthesis of polycarbonate diols beyond batch limitations
J. Dai, S. Luo, Z. Li, J. Sun, H. Sardon, N. Zhu, J. Huang and K. Guo
Polymer Chemistry Vol. 16, Núm. 32, pp. 3608–3618 10.1039/d5py00580a 12/08/2025
Lab safety alert: a real case of isocyanate exposure
A. Prasad, G. Perli, M. Ximenis, A. Tejero, A. Mugica, L. Fonseca, A. Sangroniz, F. Vidal and H. Sardon
Polymer Chemistry Vol. 16, Núm. 25, pp. 2905–2909 10.1039/d5py90051d 24/06/2025
Poly(hydroxy-oxazolidone) Thermoplastic Elastomers for Safer, Greener and Customizable Blood-Contacting Medical Devices
S. Melo, A. Pierrard, F. Lifrange, M. Caliari, C. D'Emal, M. Debuisson, H. Sardon, P. Delvenne, P. Lancellotti, C. Detrembleur, C. Jerome and C. Oury
Advanced Healthcare Materials Vol. 14, Núm. 23 10.1002/adhm.202502670 19/06/2025
What decades of plastics waste management have taught us
C. Jehanno, M. Ximenis, L. Breloy, O. Akin, R. Kol, K. Van Geem, S. De Meester and H. Sardon
Nature Reviews Materials Vol. 10, Núm. 10, pp. 715–716 10.1038/s41578-025-00820-3 10/06/2025
Recyclable polyolefin-like materials with weakened all-carbon backbones
L. Breloy and H. Sardon
Nature Chemical Engineering Vol. 2, Núm. 2, pp. 97–98 10.1038/s44286-025-00175-0 01/02/2025
Reformation by light
X. Lopez de Pariza and H. Sardon
SCIENCE Vol. 388, Núm. 6743, pp. 148–149 10.1126/science.adw9160 01/01/2025
Toward a Circular Economy of Heteroatom Containing Plastics: A Focus on Heterogeneous Catalysis in Recycling
G. Perli, I. Olazabal, L. Breloy, I. Vollmer, F. López-Gallego and H. Sardon
LANGMUIR Vol. 41, Núm. 10, pp. 6429–6456 10.1021/acs.langmuir.4c04015 01/01/2025
Controlling the cis/trans Content of Biobased Unsaturated Polyesters by Judicious Choice of a Biosourced Catalyst
C. Morand, D. Mantione, A. Dove, H. Sardón and C. Jehanno
ACS Sustainable Chemistry & Engineering Vol. 13, Núm. 17, pp. 6176–6185 10.1021/acssuschemeng.4c10451 01/01/2025
Upcycling Commodity Styrofoam into Redox Polymer-based Electrodes
A. Oh Biying, S. Trano, Y. Eng, G. Lingua, H. Sardon, D. Mecerreyes and J. Chan
ChemSusChem Vol. 18, Núm. 11 10.1002/cssc.202500092 01/01/2025
Nanostructured films from poly(3-hexylthiophene)-graft-poly(?-caprolactone) as light-responsive generators of reactive oxygen species
I. Aziz, E. Gabirondo, A. Flores, P. Posadas, H. Sardon, D. Mecerreyes and M. Criado-Gonzalez
Nanoscale Vol. 17, Núm. 17, pp. 10677–10684 10.1039/d5nr00027k 01/01/2025
Sustainable and biobased self-blown polycarbonate foams: from synthesis to application
T. Abbasoglu, X. Lopez de Pariza, G. Perli, D. Merino, P. Caillard-Humeau, A. Duval, L. Avérous, L. Irusta, A. González and H. Sardon
GREEN CHEMISTRY Vol. 27, Núm. 16, pp. 4341–4351 10.1039/d4gc06429a 01/01/2025
Implementing recyclable bio- and CO2-sourced synergetic dynamic matrices via precise control of curing and properties for natural fiber composites within industrially relevant resin transfer molding
G. Seychal, B. Campos, G. Perli, V. Placet, B. Grignard, F. Bonnet, C. Detrembleur, H. Sardon, N. Aranburu and J. Raquez
Chemical Engineering Journal Vol. 511 10.1016/j.cej.2025.161506 01/01/2025
Depolymerizing off-the-shelf polymethacrylates with visible light
N. Ballard and H. Sardon
Chem Vol. 11, Núm. 4 10.1016/j.chempr.2025.102540 01/01/2025
Fully Recyclable Pluripotent Networks for 3D Printing Enabled by Dissociative Dynamic Bonds
M. Caliari, F. Vidal, D. Mantione, G. Seychal, M. Campoy-Quiles, L. Irusta, M. Fernandez, X. de Pariza, T. Habets, N. Aramburu, J. Raquez, B. Grignard, A.J. Müller, C. Detrembleur and H. Sardon
ADVANCED MATERIALS Vol. 37, Núm. 15 10.1002/adma.202417355 01/01/2025
Comparative Life Cycle Assessment of Recyclable Polyhydroxyurethanes Synthesized from Five- and Six-Membered Carbonates
P. Bron, O. Talon, C. Bakkali-Hassani, L. Irusta, H. Sardon, V. Ladmiral and S. Caillol
Macromol Vol. 5, Núm. 1 10.3390/macromol5010012 01/01/2025
Dynamic by design: unlocking full relaxation in disulfide epoxy networks
P. Fanlo, O. Konuray, O. Ochoteco, M. Ximenis, A. Rekondo, H. Grande, X. Fernández-Francos, H. Sardon and A. Ruiz de Luzuriaga
Polymer Chemistry Vol. 16, Núm. 23, pp. 2701–2717 10.1039/d5py00124b 01/01/2025
Introduction of 9-Bromo-9-Borafluorene Scaffold Into Deep Blue Emitting p-Conjugated Polymers
J. Teotonico, D. Mantione, K. Hollister, H. Sardon, N. Ballard, F. Ruipérez, R. Gilliard and F. Vidal
JOURNAL OF POLYMER SCIENCE Vol. 63, Núm. 17, pp. 3538–3545 10.1002/pol.20241163 01/01/2025
Vat Photopolymerization of High Molecular Weight Polymer Latexes with Pseudothermoplastic Properties for Recyclability
J. Ayestaran, X. de Pariza, F. Vidal, C. Vazquez-Martel, A. Pascal, S. Yu, M. Aguirre, A. Nelson, J.R. Leiza, E. Blasco, T. Long, R. Aguirresarobe and H. Sardon
ADVANCED FUNCTIONAL MATERIALS Vol. 35, Núm. 43 10.1002/adfm.202503712 01/01/2025
Degradable Ureido-Polycarbonate Block Copolymers with a Complex UCST Thermoresponse
J. Martin-Martin, M. Abad, X. Lopez de Pariza, T. Ezquerra, A. Nogales, H. Sardon, V. Sebastián, L. Oriol and M. Piñol
MACROMOLECULAR RAPID COMMUNICATIONS Vol. 46, Núm. 14 10.1002/marc.202500029 01/01/2025
Chemical recycling of nitrogen containing polymers: processes and industrial prospects
S. Houben, M. Membrado, L. van Belleghem, I. Olazabal, N. van Velthoven, K. Vanbroekhoven, H. Sardón, D. de Vos, E. Feghali and K. Elst
PROGRESS IN POLYMER SCIENCE Vol. 168 10.1016/j.progpolymsci.2025.102002 01/01/2025
A Material Platform Based on Dissociative CO2-Derived N,O-Acetals for Tunable Degradation of 3D Printable Materials
M. Caliari, J. Teotonico, M. Irigoyen, A. Mujika, T. Isolabella, D. Mantione, L. Irusta, B. Grignard, F. Vidal, C. Detrembleur and H. Sardón
Journal of the American Chemical Society Vol. 147, Núm. 33, pp. 30095–30106 10.1021/jacs.5c07767 01/01/2025
Supramolecular driven crystallization controls polymer recycling
F. Vidal and H. Sardón
Nature Nanotechnology Vol. 20, Núm. 12, pp. 1723–1724 10.1038/s41565-025-02048-2 01/01/2025
Stereocontrolled Organocatalysis in Polymer Synthesis
G. Garbonova, L. Breloy, H. Sardón and F. Vidal
Stereocontrolled Organocatalysis In Polymer Synthesis pp. 1567–1602 10.1002/9783527845552.ch42 01/01/2025
Strain learning in protein-based mechanical metamaterials
N. Sadaba, E. Sanchez-Rexach, C. Waltmann, S. Hilburg, L. Pozzo, M. de la Cruz, H. Sardon, L. Meza and A. Nelson
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA Vol. 121, Núm. 45 10.1073/pnas.2407929121 05/11/2024
Spatio-Selective Reconfiguration of Mechanical Metamaterials Through the Use of Dynamic Covalent Chemistries
T. Abbasoglu, O. Skarsetz, P. Fanlo, B. Grignard, C. Detrembleur, A. Walther and H. Sardon
Advanced Science Vol. 11, Núm. 45 10.1002/advs.202407746 22/10/2024
How the Aliphatic Glycol Chain Length Determines the Pseudoeutectic Composition in Biodegradable Isodimorphic poly(alkylene succinate-<i>ran</i>-caprolactone) Random Copolyesters
M. Safari, J. Torres, R. Perez-Camargo, A. de Ilarduya, A. Mugica, M. Zubitur, H. Sardon, G. Liu, D. Wang and A.J. Müller
BIOMACROMOLECULES Vol. 25, Núm. 11, pp. 7392–7409 10.1021/acs.biomac.4c01073 21/10/2024
Towards a better understanding of the cosolvent effect on the low-temperature glycolysis of Polyethylene Terephthalate (PET)
E. Luna, I. Olazabal, M. Roosen, A.J. Müller, C. Jehanno, M. Ximenis, S. de Meester and H. Sardon
Chemical Engineering Journal Vol. 482 10.1016/j.cej.2024.148861 01/01/2024
A Single Amino Acid Able to Promote High-Temperature Ring-Opening Polymerization by Dual Activation
E. Gabirondo, K. Swiderek, E. Marin, A. Maiz-Iginitz, A. Larranaga, V. Moliner, A. Etxeberria and H. Sardon
Advanced Science Vol. 11, Núm. 16 10.1002/advs.202308956 01/01/2024
Organomediated polymerization
S. Honda, K. Odelius and H. Sardon
Communications Chemistry Vol. 7, Núm. 1 10.1038/s42004-024-01134-1 01/01/2024
Degradable Alternating Copolymers by Radical Copolymerization of 2-Methylen-1,3-dioxepane and Crotonate Esters
A. Barquero, A. Zanoni, E. Gabirondo, E. González de San Román, S. Hamzehlou, M. Ximenis, D. Moscatelli, H. Sardon and J.R. Leiza
ACS Macro Letters Vol. 13, Núm. 3, pp. 368–374 10.1021/acsmacrolett.4c00101 01/01/2024
Enantiodivergent biosynthesis of ß-hydroxy esters by self-sufficient heterogeneous biocatalysts in a continuous flow
D. Andrés-Sanz, A. Maiz-Iginitz, J. Bolivar, A. Orrego, H. Sardon and F. López-Gallego
GREEN CHEMISTRY Vol. 26, Núm. 8, pp. 4563–4573 10.1039/d4gc00369a 01/01/2024
Overcoming the Limitations of Organocatalyzed Glycolysis of Poly(ethylene terephthalate) to Facilitate the Recycling of Complex Waste Under Mild Conditions
I. Olazabal, E. Luna Barrios, S. De Meester, C. Jehanno and H. Sardon
ACS Applied Polymer Materials Vol. 6, Núm. 7, pp. 4226–4232 10.1021/acsapm.4c00326 01/01/2024
Design of functional isocyanate-free poly(oxazolidone)s under mild conditions
M. Razavi-Esfali, T. Habets, F. Siragusa, B. Grignard, H. Sardon and C. Detrembleur
Polymer Chemistry Vol. 15, Núm. 19, pp. 1962–1974 10.1039/d4py00101j 01/01/2024
Controlling associative transcarbamoylation reactions by light in dynamic polyurethane networks using reversible spiropyran photoswitches
G. Vozzolo, F. Elizalde, D. Mantione, R. Aguirresarobe, M. Ximenis and H. Sardon
POLYMER Vol. 302 10.1016/j.polymer.2024.127051 01/01/2024
Enhancing the incorporation of 2-methylen-1,3-dioxepane (MDO) into industrial monomers by the addition of crotonate comonomers
G. Gardoni, A. Zanoni, E. González de San Román, D. Moscatelli, E. Gabirondo, J.R. Leiza, A. Barquero and H. Sardon
POLYMER Vol. 307 10.1016/j.polymer.2024.127298 01/01/2024
A novel approach to design structural natural fiber composites from sustainable CO2-derived polyhydroxyurethane thermosets with outstanding properties and circular features
G. Seychal, P. Nickmilder, V. Lemaur, C. Ocando, B. Grignard, P. Leclère, C. Detrembleur, R. Lazzaroni, H. Sardon, N. Aranburu and J. Raquez
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING Vol. 185 10.1016/j.compositesa.2024.108311 01/01/2024
Tuning Reprocessing Temperature of Aliphatic Polyurethane Networks by Alkoxyamine Selection
F. Elizalde, V. Pertici, R. Aguirresarobe, M. Ximenis, G. Vozzolo, L. Lezama, F. Ruipérez, D. Gigmes and H. Sardon
ACS Applied Polymer Materials Vol. 6, Núm. 12, pp. 7057–7065 10.1021/acsapm.4c00840 01/01/2024
Economically competitive Organic Acid-Base mixtures as Catalysts for the Self-Condensation of Diols into Polyethers
F. Kilens, A. Olazabal, D. Mantione, A. Basterretxea, H. Sardon and C. Jehanno
ChemCatChem Vol. 16, Núm. 20 10.1002/cctc.202400215 01/01/2024
Reaction: Is a circular economy for chemicals and materials possible?
G. Perli, H. Sardon and F. Vidal
Chem Vol. 10, Núm. 7, pp. 1961–1962 10.1016/j.chempr.2024.06.025 01/01/2024
Exploiting the Base-Triggered Thiol/Vinyl Ether Addition to Prepare Well-Defined Microphase Separated Thermo-Switchable Adhesives
A. Lamas, L. Polo Fonseca, C. Moussard, D. Zanata, G. Perli, M. Ximenis, X. Lopez de Pariza, G. Seychal, M. Caliari, M. Itxaso, R. Aguirresarobe, I. Calvo and H. Sardon
ADVANCED FUNCTIONAL MATERIALS Vol. 35, Núm. 2 10.1002/adfm.202412584 01/01/2024
Synergetic Hybridization Strategy to Enhance the Dynamicity of Poorly Dynamic CO2-derived Vitrimers achieved by a Simple Copolymerization Approach
G. Seychal, M. Ximenis, V. Lemaur, B. Grignard, R. Lazzaroni, C. Detrembleur, H. Sardon, N. Aranburu and J. Raquez
ADVANCED FUNCTIONAL MATERIALS Vol. 35, Núm. 2 10.1002/adfm.202412268 01/01/2024
Mixed Isodimorphic/Isomorphic Crystallization in Aliphatic Random Copolycarbonates
Y. Liao, R. Pérez-Camargo, T. Ma, J. Maiz, A. Martínez de Ilarduya, H. Sardon, G. Liu, D. Wang and A.J. Müller
MACROMOLECULES Vol. 57, Núm. 21, pp. 10227–10239 10.1021/acs.macromol.4c01716 01/01/2024
Rheological Study of 3D Printed Semi Interpenetrated Networks
J. Ayestaran, H. Sardon, T. Long and R. Aguirresarobe
Proceedings Of The Iberian Meeting On Rheology, Ibereo 2024 Vol. 56, pp. 165–168 10.1007/978-3-031-67217-0_36 01/01/2024
A Light-Mediated, 3D-Printable, and Self-Healable Polymer Electrolyte for Lithium Batteries
F. Elizalde, S. Trano, J. Ayestarán, X. de Pariza, R. Aguirresarobe, C. Francia, D. Mecerreyes, H. Sardon and F. Bella
ADVANCED FUNCTIONAL MATERIALS Vol. 35, Núm. 8 10.1002/adfm.202419034 01/01/2024
Photobase-catalyzed thiol-ene click chemistry for light-based additive manufacturing
J. Vazquez, X. Lopez de Pariza, N. Ballinger, N. Sadaba, A. Sun, A. Olanrewaju, H. Sardon and A. Nelson
Polymer Chemistry Vol. 16, Núm. 5, pp. 589–597 10.1039/d4py01120a 01/01/2024
Unraveling the thermal stability of aromatic disulfide epoxy vitrimers: a comprehensive study using principal component analysis (PCA)
P. Fanlo, A. Ruiz de Luzuriaga, G. Albizu, M. Ximenis, A. Rekondo, H. Grande and H. Sardon
RSC Applied Polymers Vol. 2, Núm. 5, pp. 826–837 10.1039/d4lp00156g 01/01/2024
3D printed modular piezoionic sensors using dynamic covalent bonds
J. Smith-Jones, N. Ballinger, N. Sadaba, X. Lopez de Pariza, Y. Yao, S. Craig, H. Sardon and A. Nelson
RSC Applied Polymers Vol. 2, Núm. 3, pp. 434–443 10.1039/d3lp00289f 01/01/2024
Challenging Isodimorphism Concepts: Formation of Three Crystalline Phases in Poly(hexamethylene-ran-octamethylene carbonate) Copolymers.
Y. Liao, R. Perez-Camargo, H. Sardon, A. Martinez de Ilarduya, W. Hu, G. Liu, D. Wang and A.J. Müller
MACROMOLECULES Vol. 56, Núm. 20, pp. 8199–8213 10.1021/acs.macromol.3c01265 24/10/2023
Metal-free organocatalysts for high hydrolytic stability single component polyurethane adhesives and their application in decorative insulation facades manufacturing
S. Vallejos, M. Trigo-Lopez, H. Sardon, J. Gonzalez-Martin, S. Gonzalez-Moreno and J. Garcia
Construction and Building Materials Vol. 400 10.1016/j.conbuildmat.2023.132643 12/10/2023
Tailoring the Nucleation and Crystallization Rate of Polyhydroxybutyrate by Copolymerization
M. Caputo, C. Shi, X. Tang, H. Sardon, E. Chen and A.J. Müller
BIOMACROMOLECULES Vol. 24, Núm. 11, pp. 5328–5341 10.1021/acs.biomac.3c00808 01/10/2023
Disappearance of Melt Memory Effect with Comonomer Incorporation in Isodimorphic Random Copolyesters
L. Sangroniz, M. Safari, A. de Ilarduya, H. Sardon, D. Cavallo and A.J. Müller
MACROMOLECULES Vol. 56, Núm. 19, pp. 7879–7888 10.1021/acs.macromol.3c01389 21/09/2023
Polyhydroxyurethane covalent adaptable networks: looking for suitable catalysts
C. Bakkali-Hassani, D. Berne, P. Bron, L. Irusta, H. Sardon, V. Ladmiral and S. Caillol
Polymer Chemistry Vol. 14, Núm. 31, pp. 3610–3620 10.1039/d3py00579h 08/08/2023
Semiconducting Polymer Nanoporous Thin Films as a Tool to Regulate Intracellular ROS Balance in Endothelial Cells
M. Criado-Gonzalez, L. Bondi, C. Marzuoli, E. Gutierrez-Fernandez, G. Tullii, C. Ronchi, E. Gabirondo, H. Sardon, S. Rapino, M. Malferrari, T. Cramer, M. Antognazza and D. Mecerreyes
ACS Applied Materials & Interfaces Vol. 15, Núm. 30, pp. 35973–35985 10.1021/acsami.3c06633 19/07/2023
Upgrading Polyurethanes into Functional Ureas through the Asymmetric Chemical Deconstruction of Carbamates
I. Olazabal, A. Gonzalez, S. Vallejos, I. Rivilla, C. Jehanno and H. Sardon
ACS Sustainable Chemistry & Engineering Vol. 11, Núm. 1, pp. 332–342 10.1021/acssuschemeng.2c05647 01/01/2023
Polymer Colloids: Current Challenges, Emerging Applications, and New Developments
M. Aguirre, N. Ballard, E. Gonzalez, S. Hamzehlou, H. Sardon, M. Calderon, M. Paulis, R. Tomovska, D. Dupin, R. Bean, T. Long, J.R. Leiza and J. Asua
MACROMOLECULES Vol. 56, Núm. 7, pp. 2579–2607 10.1021/acs.macromol.3c00108 01/01/2023
Reducing the carbon footprint of polyurethanes by chemical and biological depolymerization: Fact or fiction?
L. Polo Fonseca, A. Duval, E. Luna, M. Ximenis, S. De Meester, L. Avérous and H. Sardon
Current Opinion in Green and Sustainable Chemistry Vol. 41 10.1016/j.cogsc.2023.100802 01/01/2023
Influence of FFF Process Conditions on the Thermal, Mechanical, and Rheological Properties of Poly(hydroxybutyrate-co-hydroxy Hexanoate)
M. Caputo, M. Fernández, R. Aguirresarobe, A. Kovalcik, H. Sardon, M. Candal and A.J. Müller
Polymers Vol. 15, Núm. 8 10.3390/polym15081817 01/01/2023
Upcycling of BPA-PC into trimethylene carbonate by solvent assisted organocatalysed depolymerisation
I. Olazabal, E. Luna, S. De Meester, C. Jehanno and H. Sardon
Polymer Chemistry Vol. 14, Núm. 19, pp. 2299–2307 10.1039/d3py00441d 01/01/2023
3D Printing of Ionic Liquid Polymer Networks for Stretchable Conductive Sensors
B. Narupai, J. Wong, E. Sanchez-Rexach, J. Smith-Jones, V. Le, N. Sadaba, H. Sardon and A. Nelson
Advanced Materials Technologies Vol. 8, Núm. 23 10.1002/admt.202300226 01/01/2023
Mechanistic studies of a lipase unveil effect of pH on hydrolysis products of small PET modules
K. Swiderek, S. Velasco-Lozano, M. Galmés, I. Olazabal, H. Sardon, F. López-Gallego and V. Moliner
Nature Communications Vol. 14, Núm. 1 10.1038/s41467-023-39201-1 01/01/2023
Bio-based non-isocyanate poly(hydroxy urethane)s (PHU) derived from vanillin and CO2
N. Fanjul-Mosteirín, L. Fonseca, A. Dove and H. Sardon
Materials Advances Vol. 4, Núm. 11, pp. 2437–2448 10.1039/d3ma00111c 01/01/2023
Introduction to Plastic Conversion
I. Vollmer, H. Sardon, G. Huber and Z. Li
Polymer Chemistry Vol. 14, Núm. 26, pp. 3054–3056 10.1039/d3py90069j 01/01/2023
Metal-free initiators pave the way for chemically recyclable polymers with industrially relevant properties
A. Sangroniz and H. Sardon
Communications Chemistry Vol. 6, Núm. 1 10.1038/s42004-023-00931-4 01/01/2023
Introduction to Plastic Conversion
I. Vollmer, H. Sardon, G. Huber and Z. Li
Catalysis Science & Technology Vol. 13, Núm. 13, pp. 3737–3739 10.1039/d3cy90036c 01/01/2023
Emerging Polyhydroxyurethanes as Sustainable Thermosets: A Structure-Property Relationship
G. Seychal, C. Ocando, L. Bonnaud, J. De Winter, B. Grignard, C. Detrembleur, H. Sardon, N. Aramburu and J. Raquez
ACS Applied Polymer Materials Vol. 5, Núm. 7, pp. 5567–5581 10.1021/acsapm.3c00879 01/01/2023
Synthesis, Morphology, and Crystallization Kinetics of Polyheptalactone (PHL)
M. Caputo, A. Olmos, B. Li, J. Olmedo-Martínez, A. Malafronte, C. De Rosa, H. Sardon, R. O’Reilly, A. Dove and A.J. Müller
BIOMACROMOLECULES Vol. 24, Núm. 7, pp. 3256–3267 10.1021/acs.biomac.3c00305 01/01/2023
Polythiourethanes: Synthesis, applications, and opportunities
X. Lopez de Pariza, P. Fanlo, L. Polo Fonseca, A. Ruiz de Luzuriaga and H. Sardon
PROGRESS IN POLYMER SCIENCE Vol. 145 10.1016/j.progpolymsci.2023.101735 01/01/2023
Recyclable photoresins for light-mediated additive manufacturing towards Loop 3D printing
X. Lopez de Pariza, O. Varela, S. Catt, T. Long, E. Blasco and H. Sardon
Nature Communications Vol. 14, Núm. 1 10.1038/s41467-023-41267-w 01/01/2023
Organocatalyzed ring-opening reactions of ?-carbonyl-substituted ?-caprolactones
T. Ota, V. Montagna, Y. Higuchi, T. Kato, M. Tanaka, H. Sardon and K. Fukushima
RSC Advances Vol. 13, Núm. 40, pp. 27764–27771 10.1039/d3ra01025b 01/01/2023
Exploiting the Use of the Decarboxylative S-Alkylation Reaction to Produce Self-Blowing, Recyclable Polycarbonate Foams
T. Abbasoglu, D. Ciardi, F. Tournilhac, L. Irusta and H. Sardon
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Vol. 62, Núm. 44 10.1002/anie.202308339 01/01/2023
Covalent Adaptable Networks through Dynamic N,S-Acetal Chemistry: Toward Recyclable CO2-Based Thermosets
T. Habets, G. Seychal, M. Caliari, J. Raquez, H. Sardon, B. Grignard and C. Detrembleur
Journal of the American Chemical Society Vol. 145, Núm. 46, pp. 25450–25462 10.1021/jacs.3c10080 01/01/2023
Thermally Reversible Organocatalyst for the Accelerated Reprocessing of Dynamic Networks with Creep Resistance
G. Vozzolo, M. Ximenis, D. Mantione, M. Fernández and H. Sardon
ACS Macro Letters Vol. 12, Núm. 11, pp. 1536–1542 10.1021/acsmacrolett.3c00544 01/01/2023
4D Printed Protein-AuNR Nanocomposites with Photothermal Shape Recovery
S. Yu, N. Sadaba, E. Sanchez-Rexach, S. Hilburg, L. Pozzo, G. Altin-Yavuzarslan, L. Liz-Marzán, D. Jimenez de Aberasturi, H. Sardon and A. Nelson
ADVANCED FUNCTIONAL MATERIALS Vol. 34, Núm. 14 10.1002/adfm.202311209 01/01/2023
A combined computational and experimental study of metathesis and nucleophile-mediated exchange mechanisms in boronic ester-containing vitrimers
J. Teotonico, D. Mantione, L. Ballester-Bayarri, M. Ximenis, H. Sardon, N. Ballard and F. Ruipérez
Polymer Chemistry Vol. 15, Núm. 3, pp. 181–192 10.1039/d3py01047c 01/01/2023
Oxime metathesis: tuneable and versatile chemistry for dynamic networks
L. Pettazzoni, M. Ximenis, F. Leonelli, G. Vozzolo, E. Bodo, F. Elizalde and H. Sardon
Chemical Science Vol. 15, Núm. 7, pp. 2359–2364 10.1039/d3sc06011j 01/01/2023
Stereocomplexed Functional and Statistical Poly(lactide-carbonate)s via a Simple Organocatalytic System
P. Bexis, J. Husband, H. Sardon, O. Coulembier and A. Dove
MACROMOLECULES Vol. 57, Núm. 5, pp. 2287–2294 10.1021/acs.macromol.3c02485 01/01/2023
Boosting the Reactivity of Bis-Lactones to Enable Step-Growth Polymerization at Room Temperature
M. Ximenis, J. Monot, E. Gabirondo, J. Jeschke, B. Martín-Vaca, D. Bourissou and H. Sardon
MACROMOLECULES Vol. 57, Núm. 7, pp. 3319–3327 10.1021/acs.macromol.3c02527 01/01/2023
Effect of Chain Stereoconfiguration on Poly(3-hydroxybutyrate) Crystallization Kinetics
M. Caputo, X. Tang, A. Westlie, H. Sardon, E. Chen and A.J. Müller
BIOMACROMOLECULES Vol. 23, Núm. 9, pp. 3847–3859 10.1021/acs.biomac.2c00682 12/09/2022
Spotting Trends in Organocatalyzed and Other Organomediated (De)polymerizations and Polymer Functionalizations
M. Valle, M. Ximenis, X. Lopez de Pariza, J. Chan and H. Sardon
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Vol. 61, Núm. 36 10.1002/anie.202203043 05/09/2022
From plastic waste to new materials for energy storage
I. Olazabal, N. Goujon, D. Mantione, M. Alvarez-Tirado, C. Jehanno, D. Mecerreyes and H. Sardon
Polymer Chemistry Vol. 13, Núm. 29, pp. 4222–4229 10.1039/d2py00592a 26/07/2022
Sustainable Green Polymerizations and End-of-Life Treatment of Polymers
D. Fagnani, C. Jehanno, H. Sardon and A. McNeil
MACROMOLECULAR RAPID COMMUNICATIONS Vol. 43, Núm. 13 10.1002/marc.202200446 01/07/2022
Self-healable dynamic poly(urea-urethane) gel electrolyte for lithium batteries
F. Elizalde, J. Amici, S. Trano, G. Vozzolo, R. Aguirresarobe, D. Versaci, S. Bodoardo, D. Mecerreyes, H. Sardon and F. Bella
Journal of Materials Chemistry A Vol. 10, Núm. 23, pp. 12588–12596 10.1039/d2ta02239g 14/06/2022
Enhanced and Reusable Poly(hydroxy urethane)-Based Low Temperature Hot-Melt Adhesives
A. Gomez-Lopez, N. Ayensa, B. Grignard, L. Irusta, I. Calvo, A.J. Müller, C. Detrembleur and H. Sardon
ACS Polymers Au Vol. 2, Núm. 3, pp. 194–207 10.1021/acspolymersau.1c00053 08/06/2022
Electroactive 3D printable poly(3,4-ethylenedioxythiophene)-graft-poly(epsilon-caprolactone) copolymers as scaffolds for muscle cell alignment
A. Dominguez-Alfaro, M. Criado-Gonzalez, E. Gabirondo, H. Lasa-Fernandez, J. Olmedo-Martinez, N. Casado, N. Alegret, A.J. Müller, H. Sardon, A. Vallejo-Illarramendi and D. Mecerreyes
Polymer Chemistry Vol. 13, Núm. 1, pp. 109–120 10.1039/d1py01185e 01/01/2022
Lactide-valerolactone copolymers for packaging applications
Sangroniz A., Sangroniz L., Hamzehlou S., Aranburu N., Sardon H., J.R. Sarasua, Iriarte M., J.R. Leiza and Etxeberria A.
Polymers Vol. 14, Núm. 1 10.3390/polym14010052 01/01/2022
Unexpected Structural Properties in the Saturation Region of the Odd-Even Effects in Aliphatic Polyethers: Influence of Crystallization Conditions
I. Flores, R. Perez-Camargo, E. Gabirondo, M. Caputo, G. Liu, D. Wang, H. Sardon and A.J. Müller
MACROMOLECULES Vol. 55, Núm. 2, pp. 584–594 10.1021/acs.macromol.1c02235 01/01/2022
Modulating the Crystallinity of a Circular Plastic towards Packaging Material with Outstanding Barrier Properties
Sangroniz A., J. Zhu, Etxeberria A., E. Chen and Sardon H.
MACROMOLECULAR RAPID COMMUNICATIONS Vol. 43, Núm. 13 10.1002/marc.202200008 01/01/2022
Internal catalysis on the opposite side of the fence in non-isocyanate polyurethane covalent adaptable networks
A. Hernández, H. Houck, F. Elizalde, M. Guerre, H. Sardon and F. Du Prez
EUROPEAN POLYMER JOURNAL Vol. 168 10.1016/j.eurpolymj.2022.111100 01/01/2022
Critical advances and future opportunities in upcycling commodity polymers
C. Jehanno, J. Alty, M. Roosen, S. De Meester, A. Dove, E. Chen, F. Leibfarth and H. Sardon
NATURE Vol. 603, Núm. 7903, pp. 803–814 10.1038/s41586-021-04350-0 01/01/2022
Unifying Step-Growth Polymerization and On-Demand Cascade Ring-Closure Depolymerization via Polymer Skeletal Editing
F. Siragusa, J. Demarteau, T. Habets, I. Olazabal, K. Robeyns, G. Evano, R. Mereau, T. Tassaing, B. Grignard, H. Sardon and C. Detrembleur
MACROMOLECULES Vol. 55, Núm. 11, pp. 4637–4646 10.1021/acs.macromol.2c00696 01/01/2022
Accelerating the Curing of Hybrid Poly(Hydroxy Urethane)-Epox y Adhesives by the Thiol-Epoxy Chemistry
A. Gomez-Lopez, B. Grignard, I. Calvo, C. Detrembleur and H. Sardon
ACS Applied Polymer Materials Vol. 4, Núm. 12, pp. 8786–8794 10.1021/acsapm.2c01195 01/01/2022
Treating the plastic problem: From renewable feedstocks and degradability to recycling
A. Dove, M. Hong, J. Lamb and H. Sardon
JOURNAL OF POLYMER SCIENCE Vol. 60, Núm. 24, pp. 3253–3255 10.1002/pol.20220698 01/01/2022
Trends in non-isocyanate polyurethane (NIPU) development
A. Gomez-Lopez, F. Elizalde, I. Calvo and H. Sardon
CHEMICAL COMMUNICATIONS Vol. 57, Núm. 92, pp. 12254–12265 10.1039/d1cc05009e 19/11/2021
Synthesis of Tailored Segmented Polyurethanes Utilizing Continuous-Flow Reactors and Real-Time Process Monitoring
X. de Pariza, T. Erdmann, P. Arrechea, L. Perez, C. Dausse, N. Park, J. Hedrick and H. Sardon
CHEMISTRY OF MATERIALS Vol. 33, Núm. 20, pp. 7986–7993 10.1021/acs.chemmater.1c01919 26/10/2021
Crystallization-Induced Gelling as a Method to 4D Print Low-Water-Content Non-isocyanate Polyurethane Hydrogels
N. Fanjul-Mosteirin, R. Aguirresarobe, N. Sadaba, A. Larranaga, E. Marin, J. Martin, N. Ramos-Gomez, M. Arno, H. Sardon and A. Dove
CHEMISTRY OF MATERIALS Vol. 33, Núm. 18, pp. 7194–7202 10.1021/acs.chemmater.1c00913 28/09/2021
From Lab to Market: Current Strategies for the Production of Biobased Polyols
H. Sardon, D. Mecerreyes, A. Basterretxea, L. Averous and C. Jehanno
ACS Sustainable Chemistry & Engineering Vol. 9, Núm. 32, pp. 10664–10677 10.1021/acssuschemeng.1c02361 16/08/2021
Solid-Solid Crystal Transitions (delta to alpha) in Poly(hexamethylene carbonate) and Poly(octamethylene carbonate)
R. Perez-Camargo, G. Liu, L. Meabe, Y. Zhao, H. Sardon, D. Wang and A.J. Müller
MACROMOLECULES Vol. 54, Núm. 15, pp. 7258–7268 10.1021/acs.macromol.1c01188 10/08/2021
Novel imino- and aryl-sulfonate based photoacid generators for the cationic ring-opening polymerization of epsilon-caprolactone
X. de Pariza, E. Jara, N. Zivic, F. Ruiperez, T. Long and H. Sardon
Polymer Chemistry Vol. 12, Núm. 28, pp. 4035–4042 10.1039/d1py00734c 28/07/2021
Stereoretention in the Bulk ROP of L-Lactide Guided by a Thermally Stable Organocatalyst
A. Basterretxea, E. Gabirondo, C. Jehanno, H. Zhu, O. Coulembier, D. Mecerreyes and H. Sardon
MACROMOLECULES Vol. 54, Núm. 13, pp. 6214–6225 10.1021/acs.macromol.1c01060 13/07/2021
Chemically recyclable glycerol-biobased polyether thermosets
A. Gallastegui, E. Gabirondo, F. Elizalde, N. Aranburu, D. Mecerreyes and H. Sardon
EUROPEAN POLYMER JOURNAL Vol. 143 10.1016/j.eurpolymj.2020.110174 01/01/2021
Healable and self-healing polyurethanes using dynamic chemistry
R. Aguirresarobe, S. Nevejans, B. Reck, L. Irusta, H. Sardon, J. Asua and N. Ballard
PROGRESS IN POLYMER SCIENCE Vol. 114 10.1016/j.progpolymsci.2021.101362 01/01/2021
Plastics in our ocean as transdisciplinary challenge
M. Riechers, L. Fanini, A. Apicella, C. Galván, E. Blondel, B. Espiña, S. Kefer, T. Keroullé, K. Klun, T. Pereira, F. Ronchi, P. Rodríguez, H. Sardon, A. Silva, M. Stulgis and N. Ibarra-González
Marine Pollution Bulletin Vol. 164 10.1016/j.marpolbul.2021.112051 01/01/2021
Synergetic Effect of Dopamine and Alkoxysilanes in Sustainable Non-Isocyanate Polyurethane Adhesives
A. Gomez-Lopez, B. Grignard, I. Calvo, C. Detrembleur and H. Sardon
MACROMOLECULAR RAPID COMMUNICATIONS Vol. 42, Núm. 3 10.1002/marc.202000538 01/01/2021
Methoxy-Functionalized Glycerol-Based Aliphatic Polycarbonate: Organocatalytic Synthesis, Blood Compatibility, and Hydrolytic Property
V. Montagna, J. Takahashi, M. Tsai, T. Ota, N. Zivic, S. Kawaguchi, T. Kato, M. Tanaka, H. Sardon and K. Fukushima
ACS Biomaterials Science & Engineering Vol. 7, Núm. 2, pp. 472–481 10.1021/acsbiomaterials.0c01460 01/01/2021
Organocatalyzed closed-loop chemical recycling of thermo-compressed films of poly(ethylene furanoate)
E. Gabirondo, B. Melendez-Rodriguez, C. Arnal, J. Lagaron, A. Martínez De Ilarduya, H. Sardon and S. Torres-Giner
Polymer Chemistry Vol. 12, Núm. 10, pp. 1571–1580 10.1039/d0py01623c 01/01/2021
Physical aging behavior of a glassy polyether
X. Monnier, S. Marina, X. De Pariza, H. Sardón, J. Martin and D. Cangialosi
Polymers Vol. 13, Núm. 6 10.3390/polym13060954 01/01/2021
3D-Printed Bioplastics with Shape-Memory Behavior Based on Native Bovine Serum Albumin
E. Sanchez-Rexach, P. Smith, A. Gomez-Lopez, M. Fernandez, A. Cortajarena, H. Sardon and A. Nelson
ACS Applied Materials & Interfaces Vol. 13, Núm. 16, pp. 19193–19199 10.1021/acsami.0c22377 01/01/2021
Polymorphism in Non-Fullerene Acceptors Based on Indacenodithienothiophene
S. Marina, A. Scaccabarozzi, E. Gutierrez-Fernandez, E. Solano, A. Khirbat, L. Ciammaruchi, A. Iturrospe, A. Balzer, L. Yu, E. Gabirondo, X. Monnier, H. Sardon, T. Anthopoulos, M. Caironi, M. Campoy-Quiles, C. Müller, D. Cangialosi, N. Stingelin and J. Martin
ADVANCED FUNCTIONAL MATERIALS Vol. 31, Núm. 29 10.1002/adfm.202103784 01/01/2021
Exploring the advantages of oxygen-tolerant thiol-ene polymerization over conventional acrylate free radical photopolymerization processes for pressure-sensitive adhesives
O. Llorente, A. Agirre, I. Calvo, M. Olaso, R. Tomovska and H. Sardon
POLYMER JOURNAL Vol. 53, Núm. 11, pp. 1195–1204 10.1038/s41428-021-00520-z 01/01/2021
Polyether single and double crystalline blends and the effect of lithium salt on their crystallinity and ionic conductivity
J. Olmedo-Martínez, M. Pastorio, E. Gabirondo, A. Lorenzetti, H. Sardon, D. Mecerreyes and A.J. Müller
Polymers Vol. 13, Núm. 13 10.3390/polym13132097 01/01/2021
Poly(hydroxyurethane) Adhesives and Coatings: State-of-the-Art and Future Directions
A. Gomez-Lopez, S. Panchireddy, B. Grignard, I. Calvo, C. Jerome, C. Detrembleur and H. Sardon
ACS Sustainable Chemistry & Engineering Vol. 9, Núm. 29, pp. 9541–9562 10.1021/acssuschemeng.1c02558 01/01/2021
Synthesis, structure, crystallization and mechanical properties of isodimorphic PBS-ran-PCL copolyesters
M. Safari, I. Otaegi, N. Aramburu, G. Guerrica-Echevarria, A. De Ilarduya, H. Sardon and A.J. Müller
Polymers Vol. 13, Núm. 14 10.3390/polym13142263 01/01/2021
Insights on the atmospheric-pressure plasma-induced free-radical polymerization of allyl ether cyclic carbonate liquid layers
E. Niemczyk, A. Gomez-Lopez, J. Haler, G. Frache, H. Sardon and R. Quintana
Polymers Vol. 13, Núm. 17 10.3390/polym13172856 01/01/2021
Using Successive Self-Nucleation and Annealing to Detect the Solid-Solid Transitions in Poly(hexamethylene carbonate) and Poly(octamethylene carbonate)
R. Pérez-Camargo, G. Liu, L. Meabe, Y. Zhao, H. Sardon, A.J. Müller and D. Wang
MACROMOLECULES Vol. 54, Núm. 20, pp. 9670–9680 10.1021/acs.macromol.1c01856 01/01/2021
Nearly Perfect 3D Structures Obtained by Assembly of Printed Parts of Polyamide lonene Self-Healing Elastomer
K. O'Harra, N. Sadaba, M. Irigoyen, F. Ruiperez, R. Aguirresarobe, H. Sardon and J. Bara
ACS Applied Polymer Materials Vol. 2, Núm. 11, pp. 4352–4359 10.1021/acsapm.0c00799 13/11/2020
Poly(hydroxy acids) derived from the self-condensation of hydroxy acids: from polymerization to end-of-life options (vol 11, pg 4861, 2020)
E. Gabirondo, A. Sangroniz, A. Etxeberria, S. Torres-Giner and H. Sardon
Polymer Chemistry Vol. 11, Núm. 34, pp. 5548–5548 10.1039/d0py90135k 14/09/2020
Sustainable Materials and Chemical Processes for Additive Manufacturing
E. Sanchez-Rexach, T. Johnston, C. Jehanno, H. Sardon and A. Nelson
CHEMISTRY OF MATERIALS Vol. 32, Núm. 17, pp. 7105–7119 10.1021/acs.chemmater.0c02008 08/09/2020
Dynamic polyurethane thermosets: tuning associative/dissociative behavior by catalyst selection
F. Elizalde, R. Aguirresarobe, A. Gonzalez and H. Sardon
Polymer Chemistry Vol. 11, Núm. 33, pp. 5386–5396 10.1039/d0py00842g 07/09/2020
Introduction to plastics in a circular economy
H. Sardon and Z. Li
Polymer Chemistry Vol. 11, Núm. 30, pp. 4828–4829 10.1039/d0py90117b 14/08/2020
Poly(hydroxy acids) derived from the self-condensation of hydroxy acids: from polymerization to end-of-life options
E. Gabirondo, A. Sangroniz, A. Etxeberria, S. Torres-Giner and H. Sardon
Polymer Chemistry Vol. 11, Núm. 30, pp. 4861–4874 10.1039/d0py00088d 14/08/2020
Aminolytic upcycling of poly(ethylene terephthalate) wastes using a thermally-stable organocatalyst
J. Demarteau, I. Olazabal, C. Jehanno and H. Sardon
Polymer Chemistry Vol. 11, Núm. 30, pp. 4875–4882 10.1039/d0py00067a 14/08/2020
From plastic waste to polymer electrolytes for batteries through chemical upcycling of polycarbonate
K. Saito, C. Jehanno, L. Meabe, J. Olmedo-Martinez, D. Mecerreyes, K. Fukushima and H. Sardon
Journal of Materials Chemistry A Vol. 8, Núm. 28, pp. 13921–13926 10.1039/d0ta03374j 28/07/2020
Chemical Structure Drives Memory Effects in the Crystallization of Homopolymers
L. Sangroniz, A. Sangroniz, L. Meabe, A. Basterretxea, H. Sardon, D. Cavallo and A.J. Müller
MACROMOLECULES Vol. 53, Núm. 12, pp. 4874–4881 10.1021/acs.macromol.0c00751 23/06/2020
Synthesis and Characterization of Fully Biobased Copolyether Polyols
A. Basterretxea, X. Lopez de Pariza, E. Gabirondo, S. Marina, J. Martin, A. Etxeberria, D. Mecerreyes and H. Sardon
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH Vol. 59, Núm. 23, pp. 10746–10753 10.1021/acs.iecr.0c00723 10/06/2020
Selective Organocatalytic Preparation of Trimethylene Carbonate from Oxetane and Carbon Dioxide
J. Huang, C. Jehanno, J. Worch, F. Ruiperez, H. Sardon, A. Dove and O. Coulembier
ACS Catalysis Vol. 10, Núm. 10, pp. 5399–5404 10.1021/acscatal.0c00689 15/05/2020
Monocomponent Non-isocyanate Polyurethane Adhesives Based on a Sol-Gel Process
A. Gomez-Lopez, B. Grignard, I. Calvo, C. Detrembleur and H. Sardon
ACS Applied Polymer Materials Vol. 2, Núm. 5, pp. 1839–1847 10.1021/acsapm.0c00062 01/05/2020
Synthesis of Functionalized Cyclic Carbonates through Commodity Polymer Upcycling
C. Jehanno, J. Demarteau, D. Mantione, M. Arno, F. Ruiperez, J. Hedrick, A. Dove and H. Sardon
ACS Macro Letters Vol. 9, Núm. 4, pp. 443–447 10.1021/acsmacrolett.0c00164 21/04/2020
Thioxanthone-Based Photobase Generators for the Synthesis of Polyurethanes via the Photopolymerization of Polyols and Polyisocyanates
N. Zivic, N. Sadaba, N. Almandoz, F. Ruiperez, D. Mecerreyes and H. Sardon
MACROMOLECULES Vol. 53, Núm. 6, pp. 2069–2076 10.1021/acs.macromol.9b02648 24/03/2020
Influence of Chemical Structures on Isodimorphic Behavior of Three Different Copolycarbonate Random Copolymer Series
I. Arandia, L. Meabe, N. Aranburu, H. Sardon, D. Mecerreyes and A.J. Müller
MACROMOLECULES Vol. 53, Núm. 231, pp. 669–681 10.1021/acs.macromol.9b02078 28/01/2020
ROP and crystallization behaviour of partially renewable triblock aromatic-aliphatic copolymers derived from L-lactide
I. Flores, A. Martinez de Ilarduya, H. Sardon, A.J. Müller and S. Munoz-Guerra
EUROPEAN POLYMER JOURNAL Vol. 122 10.1016/j.eurpolymj.2019.109321 05/01/2020
Valorization of Plastic Wastes for the Synthesis of Imidazolium-Based Self-Supported Elastomeric Ionenes
J. Demarteau, K. O'Harra, J. Bara and H. Sardon
ChemSusChem Vol. 13, Núm. 12, pp. 3122–3126 10.1002/cssc.202000505 01/01/2020
Ionic polyureas—a novel subclass of poly(Ionic liquid)s for CO2 capture
S. Morozova, E. Lozinskaya, H. Sardon, F. Suárez-García, P. Vlasov, R. Vaudemont, Y. Vygodskii and A. Shaplov
Membranes Vol. 10, Núm. 9, pp. 1–24 10.3390/membranes10090240 01/01/2020
Selective Chemical Upcycling of Mixed Plastics Guided by a Thermally Stable Organocatalyst
C. Jehanno, J. Demarteau, D. Mantione, M. Arno, F. Ruipérez, J. Hedrick, A. Dove and H. Sardon
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Vol. 60, Núm. 12, pp. 6710–6717 10.1002/anie.202014860 01/01/2020
Photo Rheometry of Waterborne Polyurethanes for Its Implementation in Vat Photopolymerization
R. Hernandez Aguirresarobe, F. Elizalde Iraizoz, H. Sardon and A. Santamaria
Proceedings Of The Iberian Meeting On Rheology (ibereo 2019) pp. 127–131 10.1007/978-3-030-27701-7_27 01/01/2020
Benzoic Acid as an Efficient Organocatalyst for the Statistical Ring-Opening Copolymerization of epsilon-Caprolactone and L-Lactide: A Computational Investigation
C. Jehanno, L. Mezzasalma, H. Sardon, F. Ruiperez, O. Coulembier and D. Taton
MACROMOLECULES Vol. 52, Núm. 23, pp. 9238–9247 10.1021/acs.macromol.9b01853 10/12/2019
Upcycling Poly(ethylene terephthalate) Refuse to Advanced Therapeutics for the Treatment of Nosocomial and Mycobacterial Infections
J. Tan, J. Tan, N. Park, K. Xu, E. Chan, C. Yang, V. Piunova, Z. Ji, A. Lim, J. Shao, A. Bai, X. Bai, D. Mantione, H. Sardon, Y. Yang and J. Hedrick
MACROMOLECULES Vol. 52, Núm. 20, pp. 7878–7885 10.1021/acs.macromol.9b01333 22/10/2019
Organocatalyzed Polymerization of PET-mb-poly(oxyhexane) Copolymers and Their Self-Assembly into Double Crystalline Superstructures
I. Flores, A. Basterretxea, A. Etxeberria, A. Gonzalez, C. Ocando, J. Francisco Vega, J. Martinez-Salazar, H. Sardon and A.J. Müller
MACROMOLECULES Vol. 52, Núm. 18, pp. 6834–6848 10.1021/acs.macromol.9b01110 24/09/2019
Unexpected synthesis of segmented poly(hydroxyurea-urethane)s from dicyclic carbonates and diamines by organocatalysis
A. Bossion, D. Taton and H. Sardon
Abstracts Of Papers Of The American Chemical Society Vol. 258 000525061505301 25/08/2019
Designing thermally stable organocatalyst for high temperature polymerization and depolymerizations
C. Jehanno, A. Dove and H. Sardon
Abstracts Of Papers Of The American Chemical Society Vol. 258 000525061504775 25/08/2019
Packaging materials with desired mechanical and barrier properties and full chemical recyclability
A. Sangroniz, J. Zhu, X. Tang, A. Etxeberria, E. Chen and H. Sardon
Nature Communications Vol. 10, Núm. 1 10.1038/s41467-019-11525-x 08/08/2019
Dual Organocatalysts Based on Ionic Mixtures of Acids and Bases: A Step Toward High Temperature Polymerizations
A. Basterretxea, C. Jehanno, D. Mecerreyes and H. Sardon
ACS Macro Letters Vol. 8, Núm. 8, pp. 1055–1062 10.1021/acsmacrolett.9b00481 01/08/2019
Recent Advances and Challenges in the Design of Organic Photoacid and Photobase Generators for Polymerizations
N. Zivic, P. Kuroishi, F. Dumur, D. Gigmes, A. Dove and H. Sardon
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Vol. 58, Núm. 31, pp. 10410–10422 10.1002/anie.201810118 29/07/2019
Rational Study of DBU Salts for the CO2 Insertion into Epoxides for the Synthesis of Cyclic Carbonates
N. Fanjul-Mosteirin, C. Jehanno, F. Ruiperez, H. Sardon and A. Dove
ACS Sustainable Chemistry & Engineering Vol. 7, Núm. 12, pp. 10633–10640 10.1021/acssuschemeng.9b01300 17/06/2019
Synthesis of self-healable waterborne isocyanate-free poly(hydroxyurethane)-based supramolecular networks by ionic interactions
A. Bossion, I. Olazabal, R. Aguirresarobe, S. Marina, J. Martin, L. Irusta, D. Taton and H. Sardon
Polymer Chemistry Vol. 10, Núm. 21, pp. 2723–2733 10.1039/c9py00439d 07/06/2019
Synthesis and comprehensive study on industrially relevant flame retardant waterborne polyurethanes based on phosphorus chemistry
F. Tabatabaee, M. Khorasani, M. Ebrahimi, A. Gonzalez, L. Irusta and H. Sardon
PROGRESS IN ORGANIC COATINGS Vol. 131, pp. 397–406 10.1016/j.porgcoat.2019.02.042 01/06/2019
Isomorphic Polyoxyalkylene Copolyethers Obtained by Copolymerization of Aliphatic Diols
A. Basterretxea, E. Gabirondo, I. Flores, A. Etxeberria, A. Gonzalez, A.J. Müller, D. Mecerreyes, O. Coulembier and H. Sardon
MACROMOLECULES Vol. 52, Núm. 9, pp. 3506–3515 10.1021/acs.macromol.9b00469 14/05/2019
PET-ran-PLA Partially Degradable Random Copolymers Prepared by Organocatalysis: Effect of Poly(L-lactic acid) Incorporation on Crystallization and Morphology
I. Flores, A. Etxeberria, L. Irusta, I. Calafel, J. Vega, J. Martinez-Salazar, H. Sardon and A.J. Müller
ACS Sustainable Chemistry & Engineering Vol. 7, Núm. 9, pp. 8647–8659 10.1021/acssuschemeng.9b00443 06/05/2019
A step towards truly recyclable plastics
C. Jehanno and H. Sardon
NATURE Vol. 568, Núm. 7753, pp. 467–468 10.1038/d41586-019-01209-3 25/04/2019
UV-cross-linked poly(ethylene oxide carbonate) as free standing solid polymer electrolyte for lithium batteries
L. Meabe, T. Huynh, D. Mantione, L. Porcarelli, C. Li, L. O'Dell, H. Sardon, M. Armand, M. Forsyth and D. Mecerreyes
ELECTROCHIMICA ACTA Vol. 302, pp. 414–421 10.1016/j.electacta.2019.02.058 10/04/2019
Facile synthesis of medium- and long-chain aliphatic polyethers using organocatalysts
A. Basterrechea, E. Gabirondo, O. Coulembier and H. Sardon
Abstracts Of Papers Of The American Chemical Society Vol. 257 000478861206097 31/03/2019
Opportunities for organocatalysis in polymer synthesis via step-growth methods
A. Bossion, K. Heifferon, L. Meabe, N. Zivic, D. Taton, J. Hedrick, T. Long and H. Sardon
PROGRESS IN POLYMER SCIENCE Vol. 90, pp. 164–210 10.1016/j.progpolymsci.2018.11.003 01/03/2019
Synthesis of Aromatic-Aliphatic Polyesters by Enzymatic Ring Opening Polymerization of Cyclic Oligoesters and their Cyclodepolymerization for a Circular Economy
I. Flores, A. Martinez de Ilarduya, H. Sardon, A.J. Müller and S. Munoz-Guerra
ACS Applied Polymer Materials Vol. 1, Núm. 3, pp. 321–325 10.1021/acsapm.8b00265 01/03/2019
Polyether Synthesis by Bulk Self-Condensation of Diols Catalyzed by Non-Eutectic Acid-Base Organocatalysts
A. Basterretxea, E. Gabirondo, C. Jehanno, H. Zhu, I. Flores, A.J. Müller, A. Etxeberria, D. Mecerreyes, O. Coulembier and H. Sardon
ACS Sustainable Chemistry & Engineering Vol. 7, Núm. 4, pp. 4103–4111 10.1021/acssuschemeng.8b05609 18/02/2019
Organocatalysis for depolymerisation
C. Jehanno, M. Perez-Madrigal, J. Demarteau, H. Sardon and A. Dove
Polymer Chemistry Vol. 10, Núm. 2, pp. 172–186 10.1039/c8py01284a 14/01/2019
3D Printing Ionogel Auxetic Frameworks for Stretchable Sensors
J. Wong, A. Gong, P. Defnet, L. Meabe, B. Beauchamp, R. Sweet, H. Sardon, C. Cobb and A. Nelson
Advanced Materials Technologies Vol. 4, Núm. 9 10.1002/admt.201900452 01/01/2019
Organocatalyzed Step-growth Polymerization
A. Bossion, K. Heifferon, N. Zivic, T. Long and H. Sardon
RSC Polymer Chemistry Series Vol. 31, pp. 531–583 10.1039/9781788015738 01/01/2019
Chapter 12: Organocatalyzed Step-growth Polymerization
A. Bossion, K. Heifferon, N. Zivic, T. Long and H. Sardon
RSC Polymer Chemistry Series Vol. 2019-January, Núm. 31, pp. 531–583 10.1039/9781788015738-00531 01/01/2019
DNP NMR Studies of Crystalline Polymer Domains by Copolymerization with Nitroxide Radical Monomers
E. Verde-Sesto, N. Goujon, H. Sardon, P. Ruiz, Tan Vu Huynh, F. Elizalde, D. Mecerreyes, M. Forsyth and L. O'Dell
MACROMOLECULES Vol. 51, Núm. 20, pp. 8046–8053 10.1021/acs.macromol.8b01665 23/10/2018
Biodegradable Polycarbonate Iongels for Electrophysiology Measurements
A. Yuen, L. Porcarelli, R. Aguirresarobe, A. Sanchez-Sanchez, I. del Agua, U. Ismailov, G. Malliaras, D. Mecerreyes, E. Ismailova and H. Sardon
Polymers Vol. 10, Núm. 9 10.3390/polym10090989 01/09/2018
Unexpected Synthesis of Segmented Poly(hydroxyurea-urethane)s from Dicyclic Carbonates and Diamines by Organocatalysis
A. Bossion, R. Aguirresarobe, L. Irusta, D. Taton, H. Cramail, E. Grau, D. Mecerreyes, C. Su, G. Liu, A.J. Müller and H. Sardon
MACROMOLECULES Vol. 51, Núm. 15, pp. 5556–5566 10.1021/acs.macromol.8b00731 14/08/2018
Screening of different organocatalysts for the sustainable synthesis of PET
I. Flores, J. Demarteau, A.J. Müller, A. Etxeberria, L. Irusta, F. Bergman, C. Koning and H. Sardon
EUROPEAN POLYMER JOURNAL Vol. 104, pp. 170–176 10.1016/j.eurpolymj.2018.04.040 01/07/2018
Efficient polymerization and post-modification of N-substituted eight-membered cyclic carbonates containing allyl groups
A. Yuen, A. Bossion, A. Veloso, D. Mecerreyes, J. Hedrick, A. Dove and H. Sardon
Polymer Chemistry Vol. 9, Núm. 18, pp. 2458–2467 10.1039/c8py00231b 14/05/2018
Plastics recycling with a difference
H. Sardon and A. Dove
SCIENCE Vol. 360, Núm. 6387, pp. 380–381 10.1126/science.aat4997 27/04/2018
Organocatalysed depolymerisation of PET in a fully sustainable cycle using thermally stable protic ionic salt
C. Jehanno, I. Flores, A. Dove, A.J. Müller, F. Ruiperez and H. Sardon
GREEN CHEMISTRY Vol. 20, Núm. 6, pp. 1205–1212 10.1039/c7gc03396f 21/03/2018
Solid-state DNP NMR studies of crystalline polymer domains by co-polymerisation with radical monomers
H. Sardon, M. Verde, P. Ruiz, T. Huynh, D. Mecerreyes, M. Forsyth and L. O'Dell
Abstracts Of Papers Of The American Chemical Society Vol. 255 000435539906730 18/03/2018
Poly(ethylene oxide carbonates) solid polymer electrolytes for lithium batteries
L. Meabe, Tan Vu Huynh, N. Lago, H. Sardon, C. Li, L. O'Dell, M. Armand, M. Forsyth and D. Mecerreyes
ELECTROCHIMICA ACTA Vol. 264, pp. 367–375 10.1016/j.electacta.2018.01.101 20/02/2018
Catechol End-Functionalized Polylactide by Organocatalyzed Ring-Opening Polymerization
N. Sadaba, M. Salsamendi, N. Casado, E. Zuza, J. Munoz, J.R. Sarasua, D. Mecerreyes, D. Mantione, C. Detrembleur and H. Sardon
Polymers Vol. 10, Núm. 2 10.3390/polym10020155 01/02/2018
Antimicrobial polyurethane foams having cationic ammonium groups
E. Udabe, M. Isik, H. Sardon, L. Irusta, M. Salsamendi, Z. Sun, Z. Zheng, F. Yan and D. Mecerreyes
JOURNAL OF APPLIED POLYMER SCIENCE Vol. 134, Núm. 45 10.1002/app.45473 05/12/2017
Special Issue in: Organocatalyzed polymerizations
H. Sardon, A. Dove, D. Taton, O. Coulembier and A.J. Müller
EUROPEAN POLYMER JOURNAL Vol. 95, pp. 625–627 10.1016/j.eurpolymj.2017.08.047 01/10/2017
Synthesis and characterization of poly (epsilon-caprolactam-co-lactide) polyesteramides using Bronsted acid or Bronsted base organocatalyst
A. Basterretxea, E. Gabirondo, A. Sanchez-Sanchez, A. Etxeberria, O. Coulembier, D. Mecerreyes and H. Sardon
EUROPEAN POLYMER JOURNAL Vol. 95, pp. 650–659 10.1016/j.eurpolymj.2017.05.023 01/10/2017
Hydrolytically degradable poly(ethylene glycol) based polycarbonates by organocatalyzed condensation
L. Meabe, H. Sardon and D. Mecerreyes
EUROPEAN POLYMER JOURNAL Vol. 95, pp. 737–745 10.1016/j.eurpolymj.2017.06.046 01/10/2017
Easy-to-Make Carboxylic Acid Dioxythiophene Monomer (ProDOT-COOH) and Functional Conductive Polymers
D. Mantione, N. Casado, A. Sanchez-Sanchez, H. Sardon and D. Mecerreyes
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY Vol. 55, Núm. 17, pp. 2721–2724 10.1002/pola.28690 01/09/2017
Broad Spectrum Macromolecular Antimicrobials with Biofilm Disruption Capability and In Vivo Efficacy
J. Tan, D. Coady, H. Sardon, A. Yuen, S. Gao, S. Lim, Z. Liang, E. Tan, S. Venkataraman, A. Engler, M. Fevre, R. Ono, Y. Yang and J. Hedrick
Advanced Healthcare Materials Vol. 6, Núm. 16 10.1002/adhm.201601420 23/08/2017
Poly(ionic liquid)-based polyurethanes having imidazolium, ammonium, morpholinium or pyrrolidinium cations
S. Morozova, A. Shaplov, E. Lozinskaya, P. Vlasov, H. Sardon, D. Mecerreyes and Y. Vygodskii
HIGH PERFORMANCE POLYMERS Vol. 29, Núm. 6, pp. 691–703 10.1177/0954008317701551 01/08/2017
Preparation of Biodegradable Cationic Polycarbonates and Hydrogels through the Direct Polymerization of Quaternized Cyclic Carbonates
A. Yuen, E. Lopez-Martinez, E. Gomez-Bengoa, A. Cortajarena, R. Aguirresarobe, A. Bossion, D. Mecerreyes, J. Hedrick, Y. Yang and H. Sardon
ACS Biomaterials Science & Engineering Vol. 3, Núm. 8, pp. 1567–1575 10.1021/acsbiomaterials.7b00335 01/08/2017
Temperature responsive PEG-based polyurethanes "a la carte"
L. Irene Ronco, A. Basterretxea, D. Mantione, R. Aguirresarobe, R. Javier Minari, L. Marcelino Gugliotta, D. Mecerreyes and H. Sardon
POLYMER Vol. 122, pp. 117–124 10.1016/j.polymer.2017.06.043 28/07/2017
Single Ion Conducting Polymer Electrolytes Based On Versatile Polyurethanes
L. Porcarelli, K. Manojkumar, H. Sardon, O. Llorente, A. Shaplov, K. Vijayakrishna, C. Gerbaldi and D. Mecerreyes
ELECTROCHIMICA ACTA Vol. 241, pp. 526–534 10.1016/j.electacta.2017.04.132 01/07/2017
Aromatic diselenide crosslinkers to enhance the reprocessability and self-healing of polyurethane thermosets
X. An, R. Aguirresarobe, L. Irusta, F. Ruiperez, J. Matxain, X. Pan, N. Aramburu, D. Mecerreyes, H. Sardon and J. Zhu
Polymer Chemistry Vol. 8, Núm. 23, pp. 3641–3646 10.1039/c7py00448f 21/06/2017
Low-Temperature Cross-Linking of PEDOT:PSS Films Using Divinylsulfone
D. Mantione, I. del Agua, W. Schaafsma, M. ElMahmoudy, I. Uguz, A. Sanchez-Sanchez, H. Sardon, B. Castro, G. Malliaras and D. Mecerreyes
ACS Applied Materials & Interfaces Vol. 9, Núm. 21, pp. 18254–18262 10.1021/acsami.7b02296 31/05/2017
Polycondensation as a Versatile Synthetic Route to Aliphatic Polycarbonates for Solid Polymer Electrolytes
L. Meabe, N. Lago, L. Rubatat, C. Li, A.J. Müller, H. Sardon, M. Armand and D. Mecerreyes
ELECTROCHIMICA ACTA Vol. 237, pp. 259–266 10.1016/j.electacta.2017.03.217 20/05/2017
Polyurethane based organic macromolecular contrast agents (PU-ORCAs) for magnetic resonance imaging
S. Garmendia, D. Mantione, S. Alonso-de Castro, C. Jehanno, L. Lezama, J. Hedrick, D. Mecerreyes, L. Salassa and H. Sardon
Polymer Chemistry Vol. 8, Núm. 17, pp. 2693–2701 10.1039/c7py00166e 07/05/2017
Ionic Polyurethanes as a New Family of Poly(ionic liquid)s for Efficient CO2 Capture
S. Morozova, A. Shaplov, E. Lozinskaya, D. Mecerreyes, H. Sardon, S. Zulfiqar, F. Suarez-Garcia and Y. Vygodskii
MACROMOLECULES Vol. 50, Núm. 7, pp. 2814–2824 10.1021/acs.macromol.6b02812 11/04/2017
Enantioselective Ring-Opening Polymerization of rac-Lactide Dictated by Densely Substituted Amino Acids
A. Sanchez-Sanchez, I. Rivilla, M. Agirre, A. Basterretxea, A. Etxeberria, A. Veloso, H. Sardon, D. Mecerreyes and F. Cossio
Journal of the American Chemical Society Vol. 139, Núm. 13, pp. 4805–4814 10.1021/jacs.6b13080 05/04/2017
Innovative carboxylic acid functional propylene dioxythiophene (ProDOT-COOH) monomer for bioelectronics
D. Mantione, A. Sanchez-Sanchez, H. Sardon and D. Mecerreyes
Abstracts Of Papers Of The American Chemical Society Vol. 253 000430569107150 02/04/2017
Organocatalyzed synthesis of polyurethanes
H. Sardon, A. Bossion and A. Yuen
Abstracts Of Papers Of The American Chemical Society Vol. 253 000430569108033 02/04/2017
Prolines as efficient catalyst for stereocontrolled polymerization of rac-lactide
H. Sardon, A. Sanchez-Sanchez, I. Rivilla, A. Basterrechea, M. Agirre, D. Mecerreyes and F. Cossio
Abstracts Of Papers Of The American Chemical Society Vol. 253 000430569108302 02/04/2017
Non-Isocyanate Polyurethane Soft Nanoparticles Obtained by Surfactant-Assisted Interfacial Polymerization
A. Bossion, G. Jones, D. Taton, D. Mecerreyes, J. Hedrick, Z. Ong, Y. Yang and H. Sardon
LANGMUIR Vol. 33, Núm. 8, pp. 1959–1968 10.1021/acs.langmuir.6b04242 28/02/2017
Transition-metal-free synthesis of supramolecular ionic alginate-based polyurethanes
H. Daemi, M. Barikani and H. Sardon
Carbohydrate Polymers Vol. 157, pp. 1949–1954 10.1016/j.carbpol.2016.11.086 10/02/2017
Self-Assembled, Biodegradable Magnetic Resonance Imaging Agents: Organic Radical-Functionalized Diblock Copolymers
J. Chan, R. Wojtecki, H. Sardon, A. Lee, C. Smith, A. Shkumatov, S. Gao, H. Kong, Y. Yang and J. Hedrick
ACS Macro Letters Vol. 6, Núm. 2, pp. 176–180 10.1021/acsmacrolett.6b00924 01/02/2017
Amine Containing Cationic Methacrylate Copolymers as Efficient Gene Delivery Vehicles to Retinal Epithelial Cells
M. Isik, M. Agirre, J. Zarate, G. Puras, D. Mecerreyes, H. Sardon and J. Pedraz
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY Vol. 55, Núm. 2, pp. 280–287 10.1002/pola.28376 01/01/2017
Antibacterial silk fibroin/nanohydroxyapatite hydrogels with silver and gold nanoparticles for bone regeneration
M. Ribeiro, M. Ferraz, F. Monteiro, M. Fernandes, M. Beppu, D. Mantione and H. Sardon
Nanomedicine-Nanotechnology Biology and Medicine Vol. 13, Núm. 1, pp. 231–239 10.1016/j.nano.2016.08.26 01/01/2017
Effect of molecular weight on the physical properties of poly(ethylene brassylate) homopolymers
Fernández J, Amestoy H, Sardon H, Aguirre M, Varga AL and J.R. Sarasua
Journal of the Mechanical Behavior of Biomedical Materials Vol. 64, pp. 209–219 10.1016/j.jmbbm.2016.07.031 01/12/2016
Biocompatibility and hemocompatibility evaluation of polyether urethanes synthesized using DBU organocatalyst
A. Basterretxea, Y. Haga, A. Sanchez-Sanchez, M. Isik, L. Irusta, M. Tanaka, K. Fukushima and H. Sardon
EUROPEAN POLYMER JOURNAL Vol. 84, pp. 750–758 10.1016/j.eurpolymj.2016.08.008 01/11/2016
Synthesis of three different galactose-based methacrylate monomers for the production of sugar-based polymers
J. Desport, D. Mantione, M. Moreno, H. Sardon, Maria J. BARANDIARAN and D. Mecerreyes
Carbohydrate Research Vol. 432, pp. 50–54 10.1016/j.carres.2016.06.008 02/09/2016
Tuning the Selectivity of Biodegradable Antimicrobial Cationic Polycarbonates by Exchanging the Counter-Anion
Isik M, Tan JP, Ono RJ, Sanchez-Sanchez A, Mecerreyes D, Yang YY, Hedrick JL and Sardon H
MACROMOLECULAR BIOSCIENCE Vol. 16, Núm. 9, pp. 1360–1367 10.1002/mabi.201600090 01/09/2016
Organic-Acid Mediated Bulk Polymerization of epsilon-Caprolactam and Its Copolymerization with epsilon-Caprolactone
A. Sanchez-Sanchez, A. Basterretxea, D. Mantione, A. Etxeberria, C. Elizetxea, A. de la Calle, S. Garcia-Arrieta, H. Sardon and D. Mecerreyes
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY Vol. 54, Núm. 15, pp. 2394–2402 10.1002/pola.28114 01/08/2016
Poly(3,4-ethylenedioxythiophene):GlycosAminoGlycan Aqueous Dispersions: Toward Electrically Conductive Bioactive Materials for Neural Interfaces
Mantione D, Del Agua I, Schaafsma W, Diez-Garcia J, Castro B, Sardon H and Mecerreyes D
MACROMOLECULAR BIOSCIENCE Vol. 16, Núm. 8, pp. 1227–1238 10.1002/mabi.201600059 01/08/2016
Innovative Poly(Ionic Liquid)s by the Polymerization of Deep Eutectic Monomers
Isik M, Ruiperez F, Sardon H, Gonzalez A, Zulfiqar S and Mecerreyes D
MACROMOLECULAR RAPID COMMUNICATIONS Vol. 37, Núm. 14, pp. 1135–1142 10.1002/marc.201600026 01/07/2016
Update and challenges in organo-mediated polymerization reactions
W. Ottou, H. Sardon, D. Mecerreyes, J. Vignolle and D. Taton
PROGRESS IN POLYMER SCIENCE Vol. 56, pp. 64–115 10.1016/j.progpolymsci.2015.12.001 01/05/2016
A robust super-tough biodegradable elastomer engineered by supramolecular ionic interactions
Daemi H, Rajabi-Zeleti S, Sardon H, Barikani M, Khademhosseini A and Baharvand H
BIOMATERIALS Vol. 84, pp. 54–63 10.1016/j.biomaterials.2016.01.025 01/04/2016
Organocatalytic Anticancer Drug Loading of Degradable Polymeric Mixed Micelles via a Biomimetic Mechanism
J. Chan, J. Tan, A. Engler, X. Ke, S. Gao, C. Yang, H. Sardon, Y. Yang and J. Hedrick
MACROMOLECULES Vol. 49, Núm. 6, pp. 2013–2021 10.1021/acs.macromol.5b02784 22/03/2016
Room temperature synthesis of non-isocyanate polyurethanes (NIPUs) using highly reactive N-substituted 8-membered cyclic carbonates
A. YUEN, A. Bossion, F. Ruiperez, M. Isik, D. Mecerreyes and H. Sardon
Polymer Chemistry Vol. 7, Núm. 11, pp. 2105–2111 10.1039/c6py00264a 14/02/2016
Current trends in redox polymers for energy and medicine
N. Casado, G. Hernandez, H. Sardon and D. Mecerreyes
PROGRESS IN POLYMER SCIENCE Vol. 52, pp. 107–135 10.1016/j.progpolymsci.2015.08.003 01/01/2016
A Simple and Facile Approach to Aliphatic N-Substituted Functional Eight-Membered Cyclic Carbonates and Their Organocatalytic Polymerization
S. Venkataraman, V. Ng, D. Coady, H. Horn, G. Jones, T. Fung, H. Sardon, R. Waymouth, J. Hedrick and Y. Yang
Journal of the American Chemical Society Vol. 137, Núm. 43, pp. 13851–13860 10.1021/Jacs.5b06355 04/11/2015
Thermoresponsive Random Poly(ether urethanes) with Tailorable LCSTs for Anticancer Drug Delivery
Sardon H, Tan JP, Chan JM, Mantione D, Mecerreyes D, Hedrick JL and Yang YY
MACROMOLECULAR RAPID COMMUNICATIONS Vol. 36, Núm. 19, pp. 1761–1767 10.1002/marc.201500247 01/10/2015
Synthesis of Polyurethanes Using Organocatalysis: A Perspective
H. Sardon, A. Pascual, D. Mecerreyes, D. Taton, H. Cramail and J. Hedrick
MACROMOLECULES Vol. 48, Núm. 10, pp. 3153–3165 10.1021/acs.macromol.5b00384 26/05/2015
Broad-Spectrum Antimicrobial Polycarbonate Hydrogels with Fast Degradability
Pascual A, Tan JP, Yuen A, Chan JM, Coady DJ, Mecerreyes D, Hedrick JL, Yang YY and Sardon H
BIOMACROMOLECULES Vol. 16, Núm. 4, pp. 1169–1178 10.1021/bm501836z 13/04/2015
Organocatalytic Ring-Opening Polymerization of Trimethylene Carbonate To Yield a Biodegradable Polycarbonate
J. Chan, X. Zhang, M. Brennan, H. Sardon, A. Engler, C. Fox, C. Frank, R. Waymouth and J. Hedrick
JOURNAL OF CHEMICAL EDUCATION Vol. 92, Núm. 4, pp. 708–713 10.1021/ed500595k 01/04/2015
Experimental and Computational Studies of Ring-Opening Polymerization of Ethylene Brassylate Macrolactone and Copolymerization with epsilon-Caprolactone and TBD-Guanidine Organic Catalyst
A. Pascual, H. Sardon, F. Ruiperez, R. Gracia, P. Sudam, A. Veloso and D. Mecerreyes
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY Vol. 53, Núm. 4, pp. 552–561 10.1002/pola.27473 15/02/2015
Ionic Liquids and Cellulose: Dissolution, Chemical Modification and Preparation of New Cellulosic Materials
M. ISIK, H. SARDON MUGURUZA and D. MECERREYES MOLERO
Handbook of Ionic Liquids&Polymers 01/01/2015
Cholinium-based ion gels as solid electrolytes for long-term cutaneous electrophysiology
M. Isik, T. Lonjaret, H. Sardon, R. Marcilla, T. Herve, G. Malliaras, E. Ismailova and D. Mecerreyes
Journal of Materials Chemistry C Vol. 3, Núm. 34, pp. 8942–8948 10.1039/c5tc01888a 01/01/2015
Oxygen Barrier Properties of Waterborne Polyurethane/Silica Hybrids
H. Sardon, A. Gonzalez, M. Fernandez-Berridi and L. Irusta
Journal of Macromolecular Science Part B-Physics Vol. 54, Núm. 6, pp. 711–721 10.1080/00222348.2015.1035613 01/01/2015
Polyurethane-coated silica particles with broad-spectrum antibacterial properties
Q. Xu, H. Sardon, J. Chan, J. Hedrick and Y. Yang
Polymer Chemistry Vol. 6, Núm. 11, pp. 2011–2022 10.1039/c4py01455c 01/01/2015
Ionic liquid and cellulose technologies: Dissolution, modification and composite preparation
M. Isik, H. Sardon and D. Mecerreyes
Handbook of Ionic Liquids&Polymers pp. 135–152 10.1007/978-3-662-44903-5_6 01/01/2015
Antimicrobial hydrogels: A new weapon in the arsenal against multidrug-resistant infections
V. Ng, J. Chan, H. Sardon, R. Ono, J. Garcia, Y. Yang and J. Hedrick
ADVANCED DRUG DELIVERY REVIEWS Vol. 78, pp. 46–62 10.1016/j.addr.2014.10.028 30/11/2014
Organocatalyzed Synthesis of Aliphatic Polyesters from Ethylene Brassy late: A Cheap and Renewable Macrolactone
A. Pascual, H. Sardon, A. Veloso, F. Ruiperez and D. Mecerreyes
ACS Macro Letters Vol. 3, Núm. 9, pp. 849–853 10.1021/mz500401u 01/09/2014
Kimika kuantikoaren erabilera materialen zientzian: polimerizazio-erreakzioetatik trantsizio-metalen agregatuetara
A. PASCUAL, A. VELOSO FERNÁNDEZ, H. SARDON MUGURUZA, J. Ugalde, I. Infante, D. MECERREYES MOLERO and F. RUIPEREZ CILLAN
II. Materialen Zientzia eta Teknologia Kongresua Vol. 1, pp. 155–158 02/07/2014
Ionic Liquids and Cellulose: Dissolution, Chemical Modification and Preparation of New Cellulosic Materials
M. Isik, H. Sardon and D. Mecerreyes
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES Vol. 15, Núm. 7, pp. 11922–11940 10.3390/ijms150711922 01/07/2014
Highly tunable polyurethanes: organocatalyzed polyaddition and subsequent post-polymerization modification of pentafluorophenyl ester sidechains
H. Sardon, J. Chan, R. Ono, D. Mecerreyes and J. Hedrick
Polymer Chemistry Vol. 5, Núm. 11, pp. 3547–3550 10.1039/c4py00262h 01/01/2014
New amphiphilic block copolymers from lactic acid and cholinium building units
M. Isik, H. Sardon, M. Saenz and D. Mecerreyes
RSC Advances Vol. 4, Núm. 96, pp. 53407–53410 10.1039/c4ra10063h 01/01/2014
Chemically modifiable N-heterocycle-functionalized polycarbonates as a platform for diverse smart biomimetic nanomaterials
J. Chan, X. Ke, H. Sardon, A. Engler, Y. Yang and J. Hedrick
Chemical Science Vol. 5, Núm. 8, pp. 3294–3300 10.1039/c4sc00789a 01/01/2014
Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate
D. Sanders, D. Coady, M. Yasumoto, M. Fujiwara, H. Sardon and J. Hedrick
Polymer Chemistry Vol. 5, Núm. 2, pp. 327–329 10.1039/c3py01128c 01/01/2014
Organic Acid-Catalyzed Polyurethane Formation via a Dual-Activated Mechanism: Unexpected Preference of N-Activation over O-Activation of Isocyanates
H. Sardon, A. Engler, J. Chan, J. Garcia, D. Coady, A. Pascual, D. Mecerreyes, G. Jones, J. Rice, H. Horn and J. Hedrick
Journal of the American Chemical Society Vol. 135, Núm. 43, pp. 16235–16241 10.1021/ja408641g 30/10/2013
Tetra-n-butylammonium Fluoride as an Efficient Transesterification Catalyst for Functionalizing Cyclic Carbonates and Aliphatic Polycarbonates
J. Chan, H. Sardon, A. Engler, J. Garcia and J. Hedrick
ACS Macro Letters Vol. 2, Núm. 10, pp. 860–864 10.1021/mz400334j 01/10/2013
Aqueous-phase polyurethane synthesis from activated carbonates under isocyanate- and catalyst-free conditions
H. Sardon, J. Chan, A. Engler, J. O'Brien, D. Coady, J. Hedrick and D. Mecerreyes
Abstracts Of Papers Of The American Chemical Society Vol. 246 000329618407082 08/09/2013
Synthesis and post-polymerization modification of a polycarbonate containing a pendant activated ester
A. Engler, J. Chan, D. Coady, J. O'Brien, H. Sardon and J. Hedrick
Abstracts Of Papers Of The American Chemical Society Vol. 246 000329618407083 08/09/2013
Waterborne hybrid polyurethane coatings functionalized with (3-aminopropyl)triethoxysilane: Adhesion properties
H. Sardon, L. Irusta, A. Gonzalez and M. Fernandez-Berridi
PROGRESS IN ORGANIC COATINGS Vol. 76, Núm. 9, pp. 1230–1235 10.1016/j.porgcoat.2013.03.025 01/09/2013
Biodegradable water soluble polymers as an alternative to PEG
D. Coady, H. Sardon, Y. Yang and J. Hedrick
Abstracts Of Papers Of The American Chemical Society Vol. 245 000324303605147 07/04/2013
Polymerizing Base Sensitive Cyclic Carbonates Using Acid Catalysis
D. Coady, H. Horn, G. Jones, H. Sardon, A. Engler, R. Waymouth, J. Rice, Y. Yang and J. Hedrick
ACS Macro Letters Vol. 2, Núm. 4, pp. 306–312 10.1021/mz3006523 01/04/2013
Accessing New Materials through Polymerization and Modification of a Polycarbonate with a Pendant Activated Ester
A. Engler, J. Chan, D. Coady, J. O'Brien, H. Sardon, A. Nelson, D. Sanders, Y. Yang and J. Hedrick
MACROMOLECULES Vol. 46, Núm. 4, pp. 1283–1290 10.1021/ma4001258 26/02/2013
Homogeneous isocyanate- and catalyst-free synthesis of polyurethanes in aqueous media
H. Sardon, A. Engler, J. Chan, D. Coady, J. O'Brien, D. Mecerreyes, Y. Yang and J. Hedrick
GREEN CHEMISTRY Vol. 15, Núm. 5, pp. 1121–1126 10.1039/c3gc40319j 01/01/2013
Assessment of Histogel, a biomaterial derived from Wharton's jelly for tissue engineering product applications
H. Rapoport, H. Sardon, A. Herrero-Mendez, M. Granado and B. Castro
24th European Conference On Biomaterials pp. 15–20 000319162200003 01/01/2011