Itxaso Calafel Martinez


Research Staff

Coordinator

Física de polímeros y fabricación avanzada

Reología y fabricación avanzada

+34943015446/8494

itxaso.calafel@ehu.eus



M. Itxaso Calafel holds a degree in Chemical Sciences and a PhD from the University of the Basque Country (EHU), and her career has focused on the rheology and processing of advanced polymeric materials. From 1994 to 2006, she worked in the Thermal Analysis Group at the Faculty of Chemistry in San Sebastian, before joining the Rheology and Additive Manufacturing Group at POLYMAT Institute (EHU) in 2007. Since 2022, she has been a researcher at POLYMAT FUNDAZIOA and, since 2021, an Assistant Professor at the Faculty of Chemistry. She has participated in regional, national and European research projects, collaborated with universities, research institutions and companies, published in peer-reviewed journals, contributed to scientific conferences and supervised Bachelor’s, Master’s and doctoral research. She has also delivered Applied Rheology courses for industry professionals. Her early research addressed phase separation in epoxy systems modified with semicrystalline thermoplastics, including crystallisation and curing kinetics. She later worked on PVC homopolymers and vinyl chloride copolymers produced through single-electron transfer living radical polymerisation (SET-LRP). A major part of her research has subsequently focused on additive manufacturing, particularly the rheological parameters that determine the printability of materials ranging from homopolymers and polymer blends to copolymers, hydrogels and composites. Her work covers different manufacturing techniques, including melt extrusion, photopolymerisation and sintering. Her current research explores high-value biodegradable materials, including smart foamable formulations with stimulus-responsive properties, as well as hydrogels for ophthalmic applications. More broadly, she is interested in understanding structure-processing-property relationships through rheology and applying this knowledge within multidisciplinary research and industrial collaborations.

3D printable polybutylene-succinate-co-adipate/carbon nanotube conductive nanocomposites: Effect of shearing on electrical conductivity
Pascal A., Iruretagoyena E., Calafel M.I., Fernández M., Guerrica-Echevarria G., Aranburu N. and Aguirresarobe R.
POLYMER Vol. 356 10.1016/j.polymer.2026.130032 01/01/2026
Hierarchical tuning of viscoelasticity in tetra-PEG hydrogels via Au(I)–thiolate coordination
Insua I., Aguirresarobe R., de Souza Nunes J., Dupin D., Acera A., Calafel I. and Fernandez M.
POLYMER Vol. 356 10.1016/j.polymer.2026.130042 01/01/2026
High-Molecular-Weight Isodimorphic Copolyesters with Tunable Ductility, Barrier Performance, and Adhesive Behavior
Torres-Rodríguez J., Pérez-Camargo R.A., Vidal F., Mantione D., Martínez de Ilarduya A., Aranburu N., Otaegi I., Calafel M.I., Fernandez M., Alam M.S., Sangroniz A., Sardon H. and A.J. Müller
ACS Sustainable Chemistry & Engineering Vol. 14, Núm. 31, pp. 14078–14090 10.1021/acssuschemeng.6c04613 01/01/2026
Rheology-guided experimental design of dynamically crosslinked keratin/?-carrageenan hydrogels as potential drug delivery systems
Fratini C., Tiboni M., Calafel I., Fernández M., Aguirresarobe R., Aluigi A. and Casettari L.
Carbohydrate Polymers Vol. 391 10.1016/j.carbpol.2026.125842 01/01/2026
Recycling of Epoxy Resin via Blending with Polycaprolactone for Fused Filament Fabrication 3D Printing Applications
I. Razquin, L. Mediavilla, M. Cobos, I. Insua, I. Calafel, N. Aranburu, I. Larraza, L. Martin, A. Gonzalez and L. Irusta
MACROMOLECULAR MATERIALS AND ENGINEERING Vol. 310, Núm. 10 10.1002/mame.202500131 15/06/2025
Rheological Insight into the 3D Printability of Carboxymethyl Cellulose-Based Hydrogels
I. Insua, O. Etzold, I. Calafel, R. Aguirresarobe, M. Calderón and M. Fernández
Gels Vol. 11, Núm. 4 10.3390/gels11040259 01/01/2025
From rheological concepts to additive manufacturing assessment of hydrogel-based materials for advanced bioprinting applications
M. Calafel, M. Criado-Gonzalez, R. Aguirresarobe, M. Fernández and C. Mijangos
Materials Advances Vol. 6, Núm. 14, pp. 4566–4597 10.1039/d5ma00019j 01/01/2025
Characterization techniques of hydrogels in healthcare
I. Insua, M. Calderón, I. Calafel, M. Fernandez and R. Aguirresarobe
Characterization Techniques Of Hydrogels In Healthcare pp. 39–84 10.1016/B978-0-443-22017-3.00012-3 01/01/2025
Continuous carbon fiber Additive Preforming and its application for the fabrication of epoxy composites
E. Hernández-Murillo, I. Otaegi, I. Calafel, L. Palenzuela, R. Mezzacasa, C. Elizetxea, G. Guerrica-Echevarría, N. Aranburu and R. Aguirresarobe
POLYMER COMPOSITES Vol. 46, Núm. 12, pp. 11243–11260 10.1002/pc.29683 01/01/2025
The influence of amniotic membrane proteins on corneal regeneration when delivered directly or using hydrogel platforms
A. Basasoro, J. Mendicute, M. Rezola, J. Burgos, M. Fernández, D. Esporrín-Ubieto, A. Sonzogni, M. Calderón, I. Calafel, A. Díaz, J. De Souza, A. Aiastui, M. Azkargorta, F. Elortza, E. Vecino and A. Acera
Frontiers in Medicine Vol. 12 10.3389/fmed.2025.1498319 01/01/2025
Additive manufacturing of semicrystalline polymers: understanding structural integrity and dimensional accuracy
M. Calafel, R. Pérez-Camargo, R. Aguirresarobe, M. Candal and A.J. Müller
Additive Manufacturing Of Semicrystalline Polymers: Understanding Structural Integrity And Dimensional Accuracy pp. 3–51 10.1016/B978-0-443-26516-7.00001-8 01/01/2025
Ammonium Salts as Curing Agents to Obtain Ionic Epoxy Resins With a Thermoplastic-to-Thermoset Transition
I. Kurowska, L. Unanue, I. Calafel, D. Otaegui, J. Olmedo-Martínez, L. Irusta, D. Vinagre, N. Aramburu, N. Casado, I. Odriozola and D. Mecerreyes
ADVANCED MATERIALS Vol. 38, Núm. 51 10.1002/adma.202516894 01/01/2025
Mechanoresponsive and Mechanoadaptative Polymeric Materials. Rheological Perspective
R. Aguirresarobe, M. Fernandéz and I. Calafel
Vol. 1514, pp. 107–142 10.1021/bk-2025-1514.ch004 01/01/2025
Flow-induced crystallization of piezoelectric poly(L-lactide) fibers by a one-step melt-spinning process
R. Schönlein, M. Fernández, I. Calafel, M. Azkune, G. Liu, A.J. Müller, J. Ugartemendia and R. Aguirresarobe
MATERIALS & DESIGN Vol. 237 10.1016/j.matdes.2023.112525 01/01/2024
Production of supertough and semiconductive PLA-based polymer blend nanocomposites by kinetic microstructural control
A. Fernández-Tena, I. Calafel, I. Otaegi, G. Guerrica-Echevarria, A.J. Müller and N. Aranburu
POLYMER Vol. 296 10.1016/j.polymer.2024.126813 01/01/2024
Development of Flame-Retardant Polylactic Acid Formulations for Additive Manufacturing
R. Aguirresarobe, I. Calafel, S. Villanueva, A. Sanchez, A. Agirre, I. Sukia, A. Esnaola and A. Saralegi
Polymers Vol. 16, Núm. 8 10.3390/polym16081030 01/01/2024
Enhancing melt strength and crystallization kinetics in polylactide: Influence of chain topology
A. Fernández-Tena, M. Fernández, A. Sandoval, M. Calafel, A. Aguirre, N. Aranburu, G. Guerrica-Echevarria, M. Di Lorenzo, A. Longo, J. Vega and A.J. Müller
International Journal of Biological Macromolecules Vol. 282, Núm. 3 10.1016/j.ijbiomac.2024.136783 01/01/2024
On the Progress of 3D Printed Hydrogels Through Fourier Transform Rheology
M. Fernandez, I. Insua, O. Etzold, M. Calderon, R. Aguirresarobe and I. Calafel
Proceedings Of The Iberian Meeting On Rheology, Ibereo 2024 Vol. 56, pp. 61–64 10.1007/978-3-031-67217-0_14 01/01/2024
Could the Poly(Lactic Acid) Be a Ductile Material? Rheological and Mechanical Study
I. Calafel, R. Aguirresarobe, A. Erkizia, P. Barari, M. Fernandez, B. Pascual, I. Conde, P. Salse and M. Tierno
Proceedings Of The Iberian Meeting On Rheology, Ibereo 2024 Vol. 56, pp. 57–60 10.1007/978-3-031-67217-0_13 01/01/2024
Rheological Aspects of Foaming Process in 3D Printing
A. Pascal, R. Aguirresarobe and I. Calafel
Proceedings Of The Iberian Meeting On Rheology, Ibereo 2024 Vol. 56, pp. 53–56 10.1007/978-3-031-67217-0_12 01/01/2024
Deciphering the Rheological Properties of 3D Printed Semi-interpenetrated Hydrogels
I. Insua, R. Aguirresarobe, M. Fernandez and I. Calafel
Proceedings Of The Iberian Meeting On Rheology, Ibereo 2024 Vol. 56, pp. 96–100 10.1007/978-3-031-67217-0_21 01/01/2024
Poly(vinyl chloride), a historical polymer still evolving
Mijangos C., Calafel I. and Santamaría A.
POLYMER Vol. 266 10.1016/j.polymer.2022.125610 01/01/2023
Shedding light on the viscoelastic behavior of artificial and human tears: A microrheological approach
J. Vega, M. Fernández, A. Cardil, I. Calafel, I. Martínez-Soroa, A. Sarriegui and A. Acera
PHYSICS OF FLUIDS Vol. 35, Núm. 7 10.1063/5.0152482 01/01/2023
The role of Eudragit® as a component of hydrogel formulations for medical devices
D. Esporrín-Ubieto, A. Sonzogni, M. Fernández, A. Acera, E. Matxinandiarena, J. Cadavid-Vargas, I. Calafel, R. Schmarsow, A.J. Müller, A. Larrañaga and M. Calderón
Journal of Materials Chemistry B Vol. 11, Núm. 38, pp. 9276–9289 10.1039/d3tb01579c 01/01/2023
Better Color and Thermal Stability of Suspension PVC Produced on an Industrial Scale by the Continuous Initiator Dosing Technology
M. Tierno, B. Pascual, J. Conde, G. Badillo, A. Hogt, K. Vanduffel, M. Calafel and A. Santamaria
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH Vol. 60, Núm. 43, pp. 15391–15402 10.1021/acs.iecr.1c02846 03/11/2021
Ternary Poly(ethylene oxide)/Poly(l, l -lactide) PEO/PLA Blends as High-Temperature Solid Polymer Electrolytes for Lithium Batteries
J. Olmedo-Martinez, L. Porcarelli, G. Guzman-Gonzalez, I. Calafel, M. Forsyth, D. Mecerreyes and A.J. Müller
ACS Applied Polymer Materials Vol. 3, Núm. 12, pp. 6326–6337 10.1021/acsapm.1c01093 01/01/2021
Searching for Rheological Conditions for FFF 3D Printing with PVC Based Flexible Compounds
I. Calafel, R. Aguirresarobe, I. Penas, A. Santamaria, M. Tierno, I. Conde and B. Pascual
Materials Vol. 13, Núm. 1, pp. 178–178 10.3390/ma13010178 01/01/2020